Self-assembly of triatomic gold units as supporting frames for a large gold diphenylphosphinite cage molecule

Christian Hollatz; Annette Schier; Jürgen Riede; Hubert Schmidbaur

doi:10.1039/a808570f

Self-assembly of triatomic gold units as supporting frames for a large gold diphenylphosphinite cage molecule

Christian Hollatz
, Annette Schier
, Jürgen Riede
, Hubert Schmidbaur

Department of Chemistry

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

46 Scopus citations

Abstract

A novel hexanuclear cage-type double-decker cation [FB-(OPPh₂Au)₃Cl₃(AuPPh₂O) ₃BF]⁺ is obtained in high yield as the tetrafluoroborate salt from a dinuclear diphenylphosphinous acid complex [Ph₂P(OH)AuCl]₂ upon treatment with BF₃·OEt₂.

Original language	English
Pages (from-to)	111-113
Number of pages	3
Journal	Journal of the Chemical Society. Dalton Transactions
Issue number	2
DOIs	https://doi.org/10.1039/a808570f
State	Published - 21 Jan 1999

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@article{2ad3eea15c1248c58945a1132e799787,

title = "Self-assembly of triatomic gold units as supporting frames for a large gold diphenylphosphinite cage molecule",

abstract = "A novel hexanuclear cage-type double-decker cation [FB-(OPPh2Au)3Cl3(AuPPh2O) 3BF]+ is obtained in high yield as the tetrafluoroborate salt from a dinuclear diphenylphosphinous acid complex [Ph2P(OH)AuCl]2 upon treatment with BF3·OEt2.",

author = "Christian Hollatz and Annette Schier and J{\"u}rgen Riede and Hubert Schmidbaur",

year = "1999",

month = jan,

day = "21",

doi = "10.1039/a808570f",

language = "English",

pages = "111--113",

journal = "Journal of the Chemical Society. Dalton Transactions",

issn = "0300-9246",

publisher = "Royal Society of Chemistry",

number = "2",

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TY - JOUR

T1 - Self-assembly of triatomic gold units as supporting frames for a large gold diphenylphosphinite cage molecule

AU - Hollatz, Christian

AU - Schier, Annette

AU - Riede, Jürgen

AU - Schmidbaur, Hubert

PY - 1999/1/21

Y1 - 1999/1/21

N2 - A novel hexanuclear cage-type double-decker cation [FB-(OPPh2Au)3Cl3(AuPPh2O) 3BF]+ is obtained in high yield as the tetrafluoroborate salt from a dinuclear diphenylphosphinous acid complex [Ph2P(OH)AuCl]2 upon treatment with BF3·OEt2.

AB - A novel hexanuclear cage-type double-decker cation [FB-(OPPh2Au)3Cl3(AuPPh2O) 3BF]+ is obtained in high yield as the tetrafluoroborate salt from a dinuclear diphenylphosphinous acid complex [Ph2P(OH)AuCl]2 upon treatment with BF3·OEt2.

UR - https://www.scopus.com/pages/publications/33748466715

U2 - 10.1039/a808570f

DO - 10.1039/a808570f

M3 - Article

AN - SCOPUS:33748466715

SN - 0300-9246

SP - 111

EP - 113

JO - Journal of the Chemical Society. Dalton Transactions

JF - Journal of the Chemical Society. Dalton Transactions

IS - 2

ER -

Self-assembly of triatomic gold units as supporting frames for a large gold diphenylphosphinite cage molecule

Abstract

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