Self-assembly of triatomic gold units as supporting frames for a large gold diphenylphosphinite cage molecule

Christian Hollatz, Annette Schier, Jürgen Riede, Hubert Schmidbaur

Research output: Contribution to journalArticlepeer-review

46 Scopus citations

Abstract

A novel hexanuclear cage-type double-decker cation [FB-(OPPh2Au)3Cl3(AuPPh2O) 3BF]+ is obtained in high yield as the tetrafluoroborate salt from a dinuclear diphenylphosphinous acid complex [Ph2P(OH)AuCl]2 upon treatment with BF3·OEt2.

Original languageEnglish
Pages (from-to)111-113
Number of pages3
JournalJournal of the Chemical Society. Dalton Transactions
Issue number2
DOIs
StatePublished - 21 Jan 1999
Externally publishedYes

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