Selective palladium-catalyzed aminocarbonylation of olefins with aromatic amines and nitroarenes

Xianjie Fang, Ralf Jackstell, Matthias Beller

Research output: Contribution to journalArticlepeer-review

162 Scopus citations

Abstract

Various olefins can be smoothly transformed in the presence of a Pd-based catalyst system and (hetero)aromatic amines or nitroarenes to synthetically interesting amides in good yields and often with high regioselectivity (see scheme). Combining this atom-efficient procedure with established functionalizations of the resulting products allows the efficient preparation of quinolines.

Original languageEnglish
Pages (from-to)14089-14093
Number of pages5
JournalAngewandte Chemie International Edition in English
Volume52
Issue number52
DOIs
StatePublished - 23 Dec 2013
Externally publishedYes

Keywords

  • alkenes
  • amides
  • aminocarbonylation
  • aromatic amines
  • nitroarenes

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