Selective external heavy atom effect on the dynamics of the isolated triplet sublevels of naphthalene X-traps

G. Weinzierl; J. Friedrich

doi:10.1016/0009-2614(81)80056-5

Selective external heavy atom effect on the dynamics of the isolated triplet sublevels of naphthalene X-traps

G. Weinzierl, J. Friedrich

Department of Physics

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

We investigated the external heavy atom effect on the dynamics of the isolated sublevels of naphthalene X-traps. The rate constants of the T^x (out of plane) and the T^y (short axis) states are selectively influenced. The heavy atom nearly exclusively affects the radiative decay. Certain symmetry restrictions may affect the external spin-orbit coupling.

Original language	English
Pages (from-to)	55-59
Number of pages	5
Journal	Chemical Physics Letters
Volume	80
Issue number	1
DOIs	https://doi.org/10.1016/0009-2614(81)80056-5
State	Published - 15 May 1981

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title = "Selective external heavy atom effect on the dynamics of the isolated triplet sublevels of naphthalene X-traps",

abstract = "We investigated the external heavy atom effect on the dynamics of the isolated sublevels of naphthalene X-traps. The rate constants of the Tx (out of plane) and the Ty (short axis) states are selectively influenced. The heavy atom nearly exclusively affects the radiative decay. Certain symmetry restrictions may affect the external spin-orbit coupling.",

author = "G. Weinzierl and J. Friedrich",

note = "Funding Information: We thank K. Fritz for his valuable assistance paring the samples_ Financial support from the Deutsche Forschungsgemeinschaft is gratefully ackncwledged.",

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AU - Friedrich, J.

N1 - Funding Information: We thank K. Fritz for his valuable assistance paring the samples_ Financial support from the Deutsche Forschungsgemeinschaft is gratefully ackncwledged.

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Y1 - 1981/5/15

N2 - We investigated the external heavy atom effect on the dynamics of the isolated sublevels of naphthalene X-traps. The rate constants of the Tx (out of plane) and the Ty (short axis) states are selectively influenced. The heavy atom nearly exclusively affects the radiative decay. Certain symmetry restrictions may affect the external spin-orbit coupling.

AB - We investigated the external heavy atom effect on the dynamics of the isolated sublevels of naphthalene X-traps. The rate constants of the Tx (out of plane) and the Ty (short axis) states are selectively influenced. The heavy atom nearly exclusively affects the radiative decay. Certain symmetry restrictions may affect the external spin-orbit coupling.

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Selective external heavy atom effect on the dynamics of the isolated triplet sublevels of naphthalene X-traps

Abstract

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