Ruthenium carbene complexes with imidazolin-2-ylidene ligands allow the formation of tetrasubstituted cycloalkenes by RCM

Lutz Ackermann; Alois Fürstner; Thomas Weskamp; Florian J. Kohl; Wolfgang A. Herrmann

doi:10.1016/S0040-4039(99)00919-3

Ruthenium carbene complexes with imidazolin-2-ylidene ligands allow the formation of tetrasubstituted cycloalkenes by RCM

Lutz Ackermann
, Alois Fürstner
, Thomas Weskamp
, Florian J. Kohl
, Wolfgang A. Herrmann

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

435 Scopus citations

Abstract

Chemically quite robust ruthenium carbene complexes 2-8 bearing one or two imidazolin-2-ylidene ligands are highly active catalysts for all types of ring closing metathesis reactions (RCM). Importantly, they even allow the formation of tetrasubstituted alkenes that were previously out of reach of ruthenium-based metathesis catalysts.

Original language	English
Pages (from-to)	4787-4790
Number of pages	4
Journal	Tetrahedron Letters
Volume	40
Issue number	26
DOIs	https://doi.org/10.1016/S0040-4039(99)00919-3
State	Published - 25 Jun 1999

Keywords

Alkenes
Carbenes
Imidazolin-2-ylidenes
Metathesis
Ruthenium

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10.1016/S0040-4039(99)00919-3

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title = "Ruthenium carbene complexes with imidazolin-2-ylidene ligands allow the formation of tetrasubstituted cycloalkenes by RCM",

abstract = "Chemically quite robust ruthenium carbene complexes 2-8 bearing one or two imidazolin-2-ylidene ligands are highly active catalysts for all types of ring closing metathesis reactions (RCM). Importantly, they even allow the formation of tetrasubstituted alkenes that were previously out of reach of ruthenium-based metathesis catalysts.",

keywords = "Alkenes, Carbenes, Imidazolin-2-ylidenes, Metathesis, Ruthenium",

author = "Lutz Ackermann and Alois F{\"u}rstner and Thomas Weskamp and Kohl, \{Florian J.\} and Herrmann, \{Wolfgang A.\}",

year = "1999",

month = jun,

day = "25",

doi = "10.1016/S0040-4039(99)00919-3",

language = "English",

volume = "40",

pages = "4787--4790",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Ltd.",

number = "26",

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TY - JOUR

T1 - Ruthenium carbene complexes with imidazolin-2-ylidene ligands allow the formation of tetrasubstituted cycloalkenes by RCM

AU - Ackermann, Lutz

AU - Fürstner, Alois

AU - Weskamp, Thomas

AU - Kohl, Florian J.

AU - Herrmann, Wolfgang A.

PY - 1999/6/25

Y1 - 1999/6/25

N2 - Chemically quite robust ruthenium carbene complexes 2-8 bearing one or two imidazolin-2-ylidene ligands are highly active catalysts for all types of ring closing metathesis reactions (RCM). Importantly, they even allow the formation of tetrasubstituted alkenes that were previously out of reach of ruthenium-based metathesis catalysts.

AB - Chemically quite robust ruthenium carbene complexes 2-8 bearing one or two imidazolin-2-ylidene ligands are highly active catalysts for all types of ring closing metathesis reactions (RCM). Importantly, they even allow the formation of tetrasubstituted alkenes that were previously out of reach of ruthenium-based metathesis catalysts.

KW - Alkenes

KW - Carbenes

KW - Imidazolin-2-ylidenes

KW - Metathesis

KW - Ruthenium

UR - https://www.scopus.com/pages/publications/0033603294

U2 - 10.1016/S0040-4039(99)00919-3

DO - 10.1016/S0040-4039(99)00919-3

M3 - Article

AN - SCOPUS:0033603294

SN - 0040-4039

VL - 40

SP - 4787

EP - 4790

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 26

ER -

Ruthenium carbene complexes with imidazolin-2-ylidene ligands allow the formation of tetrasubstituted cycloalkenes by RCM

Abstract

Keywords

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