Ruthenium and Osmium Complexes Containing NHC and π-Acid Ligands

Alexander D. Böth; Michael J. Sauer; Robert M. Reich; Fritz E. Kühn

doi:10.1016/B978-0-12-820206-7.00142-6

Ruthenium and Osmium Complexes Containing NHC and π-Acid Ligands

Alexander D. Böth
, Michael J. Sauer
, Robert M. Reich
, Fritz E. Kühn

Associate Professorship of Molecular Catalysis

Technical University of Munich

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

2 Scopus citations

Abstract

This chapter represents a comprehensive review of organometallic ruthenium and osmium complexes containing N-heterocyclic carbene as well as π-acid ligands, such as heavier tetrylenes, nitrogen and/or phosphorous coordinating ligands. Relevant literature is discussed between the years 2006 and 2020. Novel structures, reactivities and properties of these organometallic complexes are emphasized.

Original language	English
Title of host publication	Comprehensive Organometallic Chemistry IV
Subtitle of host publication	Volume 1-15
Publisher	Elsevier
Pages	444-527
Number of pages	84
Volume	1-15
ISBN (Electronic)	9780323913508
DOIs	https://doi.org/10.1016/B978-0-12-820206-7.00142-6
State	Published - 1 Jan 2022

Keywords

Catalysis
Cluster
Germylene
Hydrogenation
Medicinal chemistry
Metathesis
N-heterocyclic carbene
Nitrosyl
Organometallic complex
Osmium
Phosphine
Ruthenium
Silylene
π-Acid
π-Backbonding

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10.1016/B978-0-12-820206-7.00142-6

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title = "Ruthenium and Osmium Complexes Containing NHC and π-Acid Ligands",

abstract = "This chapter represents a comprehensive review of organometallic ruthenium and osmium complexes containing N-heterocyclic carbene as well as π-acid ligands, such as heavier tetrylenes, nitrogen and/or phosphorous coordinating ligands. Relevant literature is discussed between the years 2006 and 2020. Novel structures, reactivities and properties of these organometallic complexes are emphasized.",

keywords = "Catalysis, Cluster, Germylene, Hydrogenation, Medicinal chemistry, Metathesis, N-heterocyclic carbene, Nitrosyl, Organometallic complex, Osmium, Phosphine, Ruthenium, Silylene, π-Acid, π-Backbonding",

author = "B{\"o}th, \{Alexander D.\} and Sauer, \{Michael J.\} and Reich, \{Robert M.\} and K{\"u}hn, \{Fritz E.\}",

year = "2022",

month = jan,

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doi = "10.1016/B978-0-12-820206-7.00142-6",

language = "English",

volume = "1-15",

pages = "444--527",

booktitle = "Comprehensive Organometallic Chemistry IV",

publisher = "Elsevier",

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TY - CHAP

T1 - Ruthenium and Osmium Complexes Containing NHC and π-Acid Ligands

AU - Böth, Alexander D.

AU - Sauer, Michael J.

AU - Reich, Robert M.

AU - Kühn, Fritz E.

PY - 2022/1/1

Y1 - 2022/1/1

N2 - This chapter represents a comprehensive review of organometallic ruthenium and osmium complexes containing N-heterocyclic carbene as well as π-acid ligands, such as heavier tetrylenes, nitrogen and/or phosphorous coordinating ligands. Relevant literature is discussed between the years 2006 and 2020. Novel structures, reactivities and properties of these organometallic complexes are emphasized.

AB - This chapter represents a comprehensive review of organometallic ruthenium and osmium complexes containing N-heterocyclic carbene as well as π-acid ligands, such as heavier tetrylenes, nitrogen and/or phosphorous coordinating ligands. Relevant literature is discussed between the years 2006 and 2020. Novel structures, reactivities and properties of these organometallic complexes are emphasized.

KW - Catalysis

KW - Cluster

KW - Germylene

KW - Hydrogenation

KW - Medicinal chemistry

KW - Metathesis

KW - N-heterocyclic carbene

KW - Nitrosyl

KW - Organometallic complex

KW - Osmium

KW - Phosphine

KW - Ruthenium

KW - Silylene

KW - π-Acid

KW - π-Backbonding

UR - https://www.scopus.com/pages/publications/85148764048

U2 - 10.1016/B978-0-12-820206-7.00142-6

DO - 10.1016/B978-0-12-820206-7.00142-6

M3 - Chapter

AN - SCOPUS:85148764048

VL - 1-15

SP - 444

EP - 527

BT - Comprehensive Organometallic Chemistry IV

PB - Elsevier

ER -

Ruthenium and Osmium Complexes Containing NHC and π-Acid Ligands

Abstract

Keywords

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