Room Temperature Intermolecular Dearomatization of Arenes by an Acyclic Iminosilylene

Keyphrases

• Benzene 100%
• Arenes 100%
• Room Temperature 100%
• Aromatization 100%
• Silylenes 66%
• C-C Bond 66%
• Aromatics 66%
• Seven-membered 66%
• Ring Expansion 66%
• Substituent Effect 33%
• Silyl Group 33%
• Pyridine 33%
• DFT Calculations 33%
• Planar Geometry 33%
• Reaction Mechanism 33%
• Aryl Substituents 33%
• Computational Study 33%
• Imine Ligands 33%
• Trifluoromethyl 33%
• Effect Mechanism 33%
• Ambiphilic 33%
• Cycloheptatriene 33%
• SiC6 33%
• N-heteroarenes 33%
• N-heterocyclic Imine 33%
• Ring-expansion Reaction 33%
• Silepins 33%

Chemistry

• Ambient Reaction Temperature 100%
• Ring Expansion 100%
• Silyl Group 33%
• Silicon 33%
• Density Functional Theory 33%
• Substituent Effect 33%
• Imine 33%
• Heterocyclic Compound 33%
• Heteroarene 33%
• (Trifluoromethyl)benzene 33%
• Cycloheptatriene 33%