Reversible acyl-keten-umwandlung

Fritz R. Kreißl; Hans Keller; Wolfgang Schütt

doi:10.1016/0022-328X(92)80192-Z

Reversible acyl-keten-umwandlung

Fritz R. Kreißl, Hans Keller, Wolfgang Schütt

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Technical University of Munich

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11 Scopus citations

Abstract

Carbonyl(bistrifluoracetato)(η⁵-cyclopentadienyl)(η²-methylbenzylacyl)tungsten (5) reacts with 1,8-diazabicyclo[5.4.0]undecen (DBU) under deprotonation to give the anionic ketenyl complex [η⁵-C₅H₅(CO)(CF₃COO)₂W(OCC(H)C₆H₄CH₃][DBUH] (3). Subsequent treatment of 3 with trifluoroacetic acid trimethyloxonium tetrafluoroborate or methanol affords the original acyl complex (5), its methyl substituted derivative (6) or an ester (7).

Original language	German
Pages (from-to)	75-80
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	441
Issue number	1
DOIs	https://doi.org/10.1016/0022-328X(92)80192-Z
State	Published - 1 Dec 1992

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title = "Reversible acyl-keten-umwandlung",

abstract = "Carbonyl(bistrifluoracetato)(η5-cyclopentadienyl)(η2-methylbenzylacyl)tungsten (5) reacts with 1,8-diazabicyclo[5.4.0]undecen (DBU) under deprotonation to give the anionic ketenyl complex [η5-C5H5(CO)(CF3COO)2W(OCC(H)C6H4CH3][DBUH] (3). Subsequent treatment of 3 with trifluoroacetic acid trimethyloxonium tetrafluoroborate or methanol affords the original acyl complex (5), its methyl substituted derivative (6) or an ester (7).",

author = "Krei{\ss}l, {Fritz R.} and Hans Keller and Wolfgang Sch{\"u}tt",

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doi = "10.1016/0022-328X(92)80192-Z",

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T1 - Reversible acyl-keten-umwandlung

AU - Kreißl, Fritz R.

AU - Keller, Hans

AU - Schütt, Wolfgang

PY - 1992/12/1

Y1 - 1992/12/1

N2 - Carbonyl(bistrifluoracetato)(η5-cyclopentadienyl)(η2-methylbenzylacyl)tungsten (5) reacts with 1,8-diazabicyclo[5.4.0]undecen (DBU) under deprotonation to give the anionic ketenyl complex [η5-C5H5(CO)(CF3COO)2W(OCC(H)C6H4CH3][DBUH] (3). Subsequent treatment of 3 with trifluoroacetic acid trimethyloxonium tetrafluoroborate or methanol affords the original acyl complex (5), its methyl substituted derivative (6) or an ester (7).

AB - Carbonyl(bistrifluoracetato)(η5-cyclopentadienyl)(η2-methylbenzylacyl)tungsten (5) reacts with 1,8-diazabicyclo[5.4.0]undecen (DBU) under deprotonation to give the anionic ketenyl complex [η5-C5H5(CO)(CF3COO)2W(OCC(H)C6H4CH3][DBUH] (3). Subsequent treatment of 3 with trifluoroacetic acid trimethyloxonium tetrafluoroborate or methanol affords the original acyl complex (5), its methyl substituted derivative (6) or an ester (7).

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DO - 10.1016/0022-328X(92)80192-Z

M3 - Artikel

AN - SCOPUS:3843084386

SN - 0022-328X

VL - 441

SP - 75

EP - 80

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

Reversible acyl-keten-umwandlung

Abstract

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