Abstract
The mode-coupling theory (MCT) equations of motion for the dynamics of a hard-sphere dumbbell moving in a hard-sphere liquid were solved. Focus was on the evolution of the glassy dynamics of the reorientational degrees of freedom of a molecule. Results emphasize the importance of distinguishing between strong steric hindrance as found for large elongations of the dumbbell, and weak steric hindrance as found for small elongations.
| Original language | English |
|---|---|
| Pages (from-to) | 6934-6949 |
| Number of pages | 16 |
| Journal | Physical Review E - Statistical Physics, Plasmas, Fluids, and Related Interdisciplinary Topics |
| Volume | 61 |
| Issue number | 6 B |
| DOIs | |
| State | Published - 2000 |
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