Reductive elimination: A pathway to low-valent aluminium species

Chelladurai Ganesamoorthy; Sinah Loerke; Christian Gemel; Paul Jerabek; Manuela Winter; Gernot Frenking; Roland A. Fischer

doi:10.1039/c3cc38584a

Reductive elimination: A pathway to low-valent aluminium species

Chelladurai Ganesamoorthy, Sinah Loerke, Christian Gemel, Paul Jerabek, Manuela Winter, Gernot Frenking, Roland A. Fischer

Max-Planck-lnstitut für Kohlenforschung

Research output: Contribution to journal › Article › peer-review

82 Scopus citations

Abstract

Compounds Cp*AlH₂(1) and Cp*₂AlH (2) reductively eliminate Cp*H in benzene or toluene under reflux conditions to give Al(s) and AlCp*, respectively.

Original language	English
Pages (from-to)	2858-2860
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	28
DOIs	https://doi.org/10.1039/c3cc38584a
State	Published - 12 Mar 2013
Externally published	Yes

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@article{0697053588ce428d8109339a1a92737e,

title = "Reductive elimination: A pathway to low-valent aluminium species",

abstract = "Compounds Cp*AlH2(1) and Cp*2AlH (2) reductively eliminate Cp*H in benzene or toluene under reflux conditions to give Al(s) and AlCp*, respectively.",

author = "Chelladurai Ganesamoorthy and Sinah Loerke and Christian Gemel and Paul Jerabek and Manuela Winter and Gernot Frenking and Fischer, {Roland A.}",

year = "2013",

month = mar,

day = "12",

doi = "10.1039/c3cc38584a",

language = "English",

volume = "49",

pages = "2858--2860",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Reductive elimination

T2 - A pathway to low-valent aluminium species

AU - Ganesamoorthy, Chelladurai

AU - Loerke, Sinah

AU - Gemel, Christian

AU - Jerabek, Paul

AU - Winter, Manuela

AU - Frenking, Gernot

AU - Fischer, Roland A.

PY - 2013/3/12

Y1 - 2013/3/12

N2 - Compounds Cp*AlH2(1) and Cp*2AlH (2) reductively eliminate Cp*H in benzene or toluene under reflux conditions to give Al(s) and AlCp*, respectively.

AB - Compounds Cp*AlH2(1) and Cp*2AlH (2) reductively eliminate Cp*H in benzene or toluene under reflux conditions to give Al(s) and AlCp*, respectively.

UR - http://www.scopus.com/inward/record.url?scp=84875028869&partnerID=8YFLogxK

U2 - 10.1039/c3cc38584a

DO - 10.1039/c3cc38584a

M3 - Article

AN - SCOPUS:84875028869

SN - 1359-7345

VL - 49

SP - 2858

EP - 2860

JO - Chemical Communications

JF - Chemical Communications

IS - 28

ER -

Reductive elimination: A pathway to low-valent aluminium species

Abstract

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