Reduction of a metal-organic framework by an organometallic complex: Magnetic properties and structure of the inclusion compound [(η5- C5H5)2Co]0.5@MIL-47(V)

Mikhail Meilikhov; Kirill Yusenko; Antonio Torrisi; Bettina Jee; Caroline Mellot-Draznieks; Andreas Pöppl; Roland A. Fischer

doi:10.1002/anie.200907126

Reduction of a metal-organic framework by an organometallic complex: Magnetic properties and structure of the inclusion compound [(η⁵- C₅H₅)₂Co]_0.5@MIL-47(V)

Mikhail Meilikhov, Kirill Yusenko, Antonio Torrisi, Bettina Jee, Caroline Mellot-Draznieks, Andreas Pöppl, Roland A. Fischer

Research output: Contribution to journal › Article › peer-review

61 Scopus citations

Abstract

The stoichiometric reduction of the MIL-47(V) framework (see picture; green VO6 octahedra) was performed using cobaltocene as an organometallic reducing agent. The formation of a mixed-valence compound with a V3+/V4+ ratio of 1:1 was confirmed by magnetic susceptibility measurements. Incorporation of cobaltocene into the MIL-47(V) framework can be reversed upon treatment with water.

Original language	English
Pages (from-to)	6212-6215
Number of pages	4
Journal	Angewandte Chemie International Edition in English
Volume	49
Issue number	35
DOIs	https://doi.org/10.1002/anie.200907126
State	Published - 16 Aug 2010
Externally published	Yes

Keywords

Breathing effect
Charge-transfer
Coordination polymers
Inclusion compounds
Metal-organic frameworks

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10.1002/anie.200907126

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Meilikhov, M., Yusenko, K., Torrisi, A., Jee, B., Mellot-Draznieks, C., Pöppl, A., & Fischer, R. A. (2010). Reduction of a metal-organic framework by an organometallic complex: Magnetic properties and structure of the inclusion compound [(η⁵- C₅H₅)₂Co]_0.5@MIL-47(V). Angewandte Chemie International Edition in English, 49(35), 6212-6215. https://doi.org/10.1002/anie.200907126

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title = "Reduction of a metal-organic framework by an organometallic complex: Magnetic properties and structure of the inclusion compound [(η5- C5H5)2Co]0.5@MIL-47(V)",

abstract = "The stoichiometric reduction of the MIL-47(V) framework (see picture; green VO6 octahedra) was performed using cobaltocene as an organometallic reducing agent. The formation of a mixed-valence compound with a V3+/V4+ ratio of 1:1 was confirmed by magnetic susceptibility measurements. Incorporation of cobaltocene into the MIL-47(V) framework can be reversed upon treatment with water.",

keywords = "Breathing effect, Charge-transfer, Coordination polymers, Inclusion compounds, Metal-organic frameworks",

author = "Mikhail Meilikhov and Kirill Yusenko and Antonio Torrisi and Bettina Jee and Caroline Mellot-Draznieks and Andreas P{\"o}ppl and Fischer, {Roland A.}",

year = "2010",

month = aug,

day = "16",

doi = "10.1002/anie.200907126",

language = "English",

volume = "49",

pages = "6212--6215",

journal = "Angewandte Chemie International Edition in English",

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Meilikhov, M, Yusenko, K, Torrisi, A, Jee, B, Mellot-Draznieks, C, Pöppl, A & Fischer, RA 2010, 'Reduction of a metal-organic framework by an organometallic complex: Magnetic properties and structure of the inclusion compound [(η⁵- C₅H₅)₂Co]_0.5@MIL-47(V)', Angewandte Chemie International Edition in English, vol. 49, no. 35, pp. 6212-6215. https://doi.org/10.1002/anie.200907126

Reduction of a metal-organic framework by an organometallic complex: Magnetic properties and structure of the inclusion compound [(η⁵- C₅H₅)₂Co]_0.5@MIL-47(V). / Meilikhov, Mikhail; Yusenko, Kirill; Torrisi, Antonio et al.
In: Angewandte Chemie International Edition in English, Vol. 49, No. 35, 16.08.2010, p. 6212-6215.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Reduction of a metal-organic framework by an organometallic complex

T2 - Magnetic properties and structure of the inclusion compound [(η5- C5H5)2Co]0.5@MIL-47(V)

AU - Meilikhov, Mikhail

AU - Yusenko, Kirill

AU - Torrisi, Antonio

AU - Jee, Bettina

AU - Mellot-Draznieks, Caroline

AU - Pöppl, Andreas

AU - Fischer, Roland A.

PY - 2010/8/16

Y1 - 2010/8/16

N2 - The stoichiometric reduction of the MIL-47(V) framework (see picture; green VO6 octahedra) was performed using cobaltocene as an organometallic reducing agent. The formation of a mixed-valence compound with a V3+/V4+ ratio of 1:1 was confirmed by magnetic susceptibility measurements. Incorporation of cobaltocene into the MIL-47(V) framework can be reversed upon treatment with water.

AB - The stoichiometric reduction of the MIL-47(V) framework (see picture; green VO6 octahedra) was performed using cobaltocene as an organometallic reducing agent. The formation of a mixed-valence compound with a V3+/V4+ ratio of 1:1 was confirmed by magnetic susceptibility measurements. Incorporation of cobaltocene into the MIL-47(V) framework can be reversed upon treatment with water.

KW - Breathing effect

KW - Charge-transfer

KW - Coordination polymers

KW - Inclusion compounds

KW - Metal-organic frameworks

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U2 - 10.1002/anie.200907126

DO - 10.1002/anie.200907126

M3 - Article

AN - SCOPUS:77955972425

SN - 1433-7851

VL - 49

SP - 6212

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JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 35

ER -

Reduction of a metal-organic framework by an organometallic complex: Magnetic properties and structure of the inclusion compound [(η⁵- C₅H₅)₂Co]_0.5@MIL-47(V)

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Keywords

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