Redox Disproportionation of GeII Compounds: Synthesis and Structure of [(Me3Si)C(PMe2)2]2GeCl2 and [μ‐{(Me3Si)C(PMe2)2}]2Ge2

Hans H. Karsch; Brigitte Deubelly; Jürgen Riede; Gerhard Müller

doi:10.1002/anie.198706731

Redox Disproportionation of Ge^II Compounds: Synthesis and Structure of [(Me₃Si)C(PMe₂)₂]₂GeCl₂ and [μ‐{(Me₃Si)C(PMe₂)₂}]₂Ge₂

Hans H. Karsch
, Brigitte Deubelly
, Jürgen Riede
, Gerhard Müller

Natural Sciences

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

A longer GeGe bond than in polygermanes is found in the “bisgermanediyl” 1, which is thus in no way comparable with digermenes R₂GeGeR₂. The very stable Ge₁ compound 1 with lone pairs at the Ge centers is formed upon reaction of GeCl₂ with the phosphinomethanide [(Me₃Si)(Me₂P)₂C]^⊖ in excess. (Figure Presented.)

Original language	English
Pages (from-to)	673-674
Number of pages	2
Journal	Angewandte Chemie International Edition in English
Volume	26
Issue number	7
DOIs	https://doi.org/10.1002/anie.198706731
State	Published - Jul 1987

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title = "Redox Disproportionation of GeII Compounds: Synthesis and Structure of [(Me3Si)C(PMe2)2]2GeCl2 and [μ‐\{(Me3Si)C(PMe2)2\}]2Ge2",

abstract = "A longer GeGe bond than in polygermanes is found in the “bisgermanediyl” 1, which is thus in no way comparable with digermenes R2GeGeR2. The very stable Ge1 compound 1 with lone pairs at the Ge centers is formed upon reaction of GeCl2 with the phosphinomethanide [(Me3Si)(Me2P)2C]⊖ in excess. (Figure Presented.)",

author = "Karsch, \{Hans H.\} and Brigitte Deubelly and J{\"u}rgen Riede and Gerhard M{\"u}ller",

year = "1987",

month = jul,

doi = "10.1002/anie.198706731",

language = "English",

volume = "26",

pages = "673--674",

journal = "Angewandte Chemie International Edition in English",

issn = "0570-0833",

publisher = "John Wiley and Sons Ltd",

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T1 - Redox Disproportionation of GeII Compounds

T2 - Synthesis and Structure of [(Me3Si)C(PMe2)2]2GeCl2 and [μ‐{(Me3Si)C(PMe2)2}]2Ge2

AU - Karsch, Hans H.

AU - Deubelly, Brigitte

AU - Riede, Jürgen

AU - Müller, Gerhard

PY - 1987/7

Y1 - 1987/7

N2 - A longer GeGe bond than in polygermanes is found in the “bisgermanediyl” 1, which is thus in no way comparable with digermenes R2GeGeR2. The very stable Ge1 compound 1 with lone pairs at the Ge centers is formed upon reaction of GeCl2 with the phosphinomethanide [(Me3Si)(Me2P)2C]⊖ in excess. (Figure Presented.)

AB - A longer GeGe bond than in polygermanes is found in the “bisgermanediyl” 1, which is thus in no way comparable with digermenes R2GeGeR2. The very stable Ge1 compound 1 with lone pairs at the Ge centers is formed upon reaction of GeCl2 with the phosphinomethanide [(Me3Si)(Me2P)2C]⊖ in excess. (Figure Presented.)

UR - https://www.scopus.com/pages/publications/84985628239

U2 - 10.1002/anie.198706731

DO - 10.1002/anie.198706731

M3 - Article

AN - SCOPUS:84985628239

SN - 0570-0833

VL - 26

SP - 673

EP - 674

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 7

ER -

Redox Disproportionation of Ge^II Compounds: Synthesis and Structure of [(Me₃Si)C(PMe₂)₂]₂GeCl₂ and [μ‐{(Me₃Si)C(PMe₂)₂}]₂Ge₂

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