TY - JOUR
T1 - Recent contributions to the aqueous coordination chemistry of beryllium
AU - Schmidbaur, Hubert
PY - 2001
Y1 - 2001
N2 - The aqueous coordination chemistry and the structural chemistry of beryllium are reviewed focusing on simple fluoride, aquo, hydroxo, oxo, and peroxo complexes. Complex formation with the heavier halide and chalkogenide anions plays no role in aqueous solution. Formation and structure of beryllium carboxylates, oxo carboxylates, dicarboxylates, hydroxy-carboxylates, carbonates, phenolates, enolates, and polyolates under various pH regimes are also considered in the context of the bioinorganic chemistry of beryllium. The coordination chemistry of beryllium with amino acids is almost completely unexplored.
AB - The aqueous coordination chemistry and the structural chemistry of beryllium are reviewed focusing on simple fluoride, aquo, hydroxo, oxo, and peroxo complexes. Complex formation with the heavier halide and chalkogenide anions plays no role in aqueous solution. Formation and structure of beryllium carboxylates, oxo carboxylates, dicarboxylates, hydroxy-carboxylates, carbonates, phenolates, enolates, and polyolates under various pH regimes are also considered in the context of the bioinorganic chemistry of beryllium. The coordination chemistry of beryllium with amino acids is almost completely unexplored.
KW - Aqueous coordination chemistry
KW - Beryllium
KW - Bioinorganic chemistry of beryllium
UR - http://www.scopus.com/inward/record.url?scp=0035012183&partnerID=8YFLogxK
U2 - 10.1016/S0010-8545(00)00406-9
DO - 10.1016/S0010-8545(00)00406-9
M3 - Review article
AN - SCOPUS:0035012183
SN - 0010-8545
VL - 215
SP - 223
EP - 242
JO - Coordination Chemistry Reviews
JF - Coordination Chemistry Reviews
IS - 1
ER -