Reactions of water clusters H+(H2O)n, n = 3-75, with diethyl ether

Thomas Schindler; Christian Berg; Gereon Niedner-Schatteburg; Vladimir E. Bondybey

doi:10.1016/0301-0104(95)00288-X

Reactions of water clusters H⁺(H₂O)_n, n = 3-75, with diethyl ether

Thomas Schindler, Christian Berg, Gereon Niedner-Schatteburg, Vladimir E. Bondybey

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Technical University of Munich

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Abstract

Fragmentation and ligand exchange reactions of protonated water clusters H⁺(H₂O)_n, n = 3-75 with diethyl ether were investigated in a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer. The reactions proceed efficiently until the water core is completely "coated" by an outer layer of organic ether molecules, and relatively stable ions with H⁺(H₂O)_m[(C₂H₅)₂O]_m+2 composition are formed. These further react on a much longer time scale towards the H⁺[(C₂H₅)₂O]₂ (m = 0) final product ion.

Original language	English
Pages (from-to)	491-496
Number of pages	6
Journal	Chemical Physics
Volume	201
Issue number	2-3
DOIs	https://doi.org/10.1016/0301-0104(95)00288-X
State	Published - 15 Dec 1995

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title = "Reactions of water clusters H+(H2O)n, n = 3-75, with diethyl ether",

abstract = "Fragmentation and ligand exchange reactions of protonated water clusters H+(H2O)n, n = 3-75 with diethyl ether were investigated in a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer. The reactions proceed efficiently until the water core is completely {"}coated{"} by an outer layer of organic ether molecules, and relatively stable ions with H+(H2O)m[(C2H5)2O]m+2 composition are formed. These further react on a much longer time scale towards the H+[(C2H5)2O]2 (m = 0) final product ion.",

author = "Thomas Schindler and Christian Berg and Gereon Niedner-Schatteburg and Bondybey, {Vladimir E.}",

note = "Funding Information: Financial support by the Deutsche Forschungsge-meinschaft, by the Fonds der Chemischen Industrie and by the Commission of the European Union, program Human Capital and Mobility, is gratefully acknowledged.",

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T1 - Reactions of water clusters H+(H2O)n, n = 3-75, with diethyl ether

AU - Schindler, Thomas

AU - Berg, Christian

AU - Niedner-Schatteburg, Gereon

AU - Bondybey, Vladimir E.

N1 - Funding Information: Financial support by the Deutsche Forschungsge-meinschaft, by the Fonds der Chemischen Industrie and by the Commission of the European Union, program Human Capital and Mobility, is gratefully acknowledged.

PY - 1995/12/15

Y1 - 1995/12/15

N2 - Fragmentation and ligand exchange reactions of protonated water clusters H+(H2O)n, n = 3-75 with diethyl ether were investigated in a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer. The reactions proceed efficiently until the water core is completely "coated" by an outer layer of organic ether molecules, and relatively stable ions with H+(H2O)m[(C2H5)2O]m+2 composition are formed. These further react on a much longer time scale towards the H+[(C2H5)2O]2 (m = 0) final product ion.

AB - Fragmentation and ligand exchange reactions of protonated water clusters H+(H2O)n, n = 3-75 with diethyl ether were investigated in a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer. The reactions proceed efficiently until the water core is completely "coated" by an outer layer of organic ether molecules, and relatively stable ions with H+(H2O)m[(C2H5)2O]m+2 composition are formed. These further react on a much longer time scale towards the H+[(C2H5)2O]2 (m = 0) final product ion.

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U2 - 10.1016/0301-0104(95)00288-X

DO - 10.1016/0301-0104(95)00288-X

M3 - Article

AN - SCOPUS:21344475010

SN - 0301-0104

VL - 201

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EP - 496

JO - Chemical Physics

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ER -

Reactions of water clusters H⁺(H₂O)_n, n = 3-75, with diethyl ether

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