Reaction of anionic and cationic silicon clusters with tungsten hexafluoride studied by fourier transform ion cyclotron resonance mass spectrometry

W. D. Reents; M. L. Mandich; V. E. Bondybey

doi:10.1016/0009-2614(86)80507-3

Reaction of anionic and cationic silicon clusters with tungsten hexafluoride studied by fourier transform ion cyclotron resonance mass spectrometry

W. D. Reents, M. L. Mandich, V. E. Bondybey

Alcatel-Lucent

Research output: Contribution to journal › Article › peer-review

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Abstract

Anionic and cationic silicon clusters react exothermically with WF₆ to give a variety of tungsten and silicon fluorides. All the silicon anionic clusters transfer their charge to WF₆. The electron affinities of Si_2-6 are estimated to be less than the electron affinity of WF₆ (350 kJ mole (3.6 eV)).

Original language	English
Pages (from-to)	1-7
Number of pages	7
Journal	Chemical Physics Letters
Volume	131
Issue number	1-2
DOIs	https://doi.org/10.1016/0009-2614(86)80507-3
State	Published - 31 Oct 1986
Externally published	Yes

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title = "Reaction of anionic and cationic silicon clusters with tungsten hexafluoride studied by fourier transform ion cyclotron resonance mass spectrometry",

abstract = "Anionic and cationic silicon clusters react exothermically with WF6 to give a variety of tungsten and silicon fluorides. All the silicon anionic clusters transfer their charge to WF6. The electron affinities of Si2-6 are estimated to be less than the electron affinity of WF6 (350 kJ mole (3.6 eV)).",

author = "Reents, {W. D.} and Mandich, {M. L.} and Bondybey, {V. E.}",

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T1 - Reaction of anionic and cationic silicon clusters with tungsten hexafluoride studied by fourier transform ion cyclotron resonance mass spectrometry

AU - Reents, W. D.

AU - Mandich, M. L.

AU - Bondybey, V. E.

PY - 1986/10/31

Y1 - 1986/10/31

N2 - Anionic and cationic silicon clusters react exothermically with WF6 to give a variety of tungsten and silicon fluorides. All the silicon anionic clusters transfer their charge to WF6. The electron affinities of Si2-6 are estimated to be less than the electron affinity of WF6 (350 kJ mole (3.6 eV)).

AB - Anionic and cationic silicon clusters react exothermically with WF6 to give a variety of tungsten and silicon fluorides. All the silicon anionic clusters transfer their charge to WF6. The electron affinities of Si2-6 are estimated to be less than the electron affinity of WF6 (350 kJ mole (3.6 eV)).

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U2 - 10.1016/0009-2614(86)80507-3

DO - 10.1016/0009-2614(86)80507-3

M3 - Article

AN - SCOPUS:30544444891

SN - 0009-2614

VL - 131

SP - 1

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JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1-2

ER -

Reaction of anionic and cationic silicon clusters with tungsten hexafluoride studied by fourier transform ion cyclotron resonance mass spectrometry

Abstract

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