[Pt2(GaCp*)2(μ2-GaCp*)3]: Structure and bonding situation of the first homoleptic platinum complex with terminal and bridging Cp*Ga ligands

D. Weiss; M. Winter; R. A. Fischer; C. Yu; K. Wichmann; G. Frenking

[Pt₂(GaCp)₂(μ₂-GaCp)₃]: Structure and bonding situation of the first homoleptic platinum complex with terminal and bridging Cp*Ga ligands

D. Weiss, M. Winter, R. A. Fischer, C. Yu, K. Wichmann, G. Frenking

Max-Planck-lnstitut für Kohlenforschung

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

A new homoleptic diplatinum complex [Pt₂(GaCp*)₂(μ₂-GaCp*)₃] (Cp* = pentamethylcyclopentadienyl) exhibiting a central unit of two platinum atoms coordinated by five Cp*Ga groups acting as terminal as well as bridging ligands, was synthesized by the reaction of tris(ethylene)platinum(0) with an excess of (Cp*Ga)₆ and was characterized by structural and quantum chemical methods.

Original language	English
Pages (from-to)	2495-2496
Number of pages	2
Journal	Chemical Communications
Issue number	24
State	Published - 21 Dec 2000
Externally published	Yes

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title = "[Pt2(GaCp*)2(μ2-GaCp*)3]: Structure and bonding situation of the first homoleptic platinum complex with terminal and bridging Cp*Ga ligands",

abstract = "A new homoleptic diplatinum complex [Pt2(GaCp*)2(μ2-GaCp*)3] (Cp* = pentamethylcyclopentadienyl) exhibiting a central unit of two platinum atoms coordinated by five Cp*Ga groups acting as terminal as well as bridging ligands, was synthesized by the reaction of tris(ethylene)platinum(0) with an excess of (Cp*Ga)6 and was characterized by structural and quantum chemical methods.",

author = "D. Weiss and M. Winter and Fischer, {R. A.} and C. Yu and K. Wichmann and G. Frenking",

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journal = "Chemical Communications",

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T1 - [Pt2(GaCp*)2(μ2-GaCp*)3]

T2 - Structure and bonding situation of the first homoleptic platinum complex with terminal and bridging Cp*Ga ligands

AU - Weiss, D.

AU - Winter, M.

AU - Fischer, R. A.

AU - Yu, C.

AU - Wichmann, K.

AU - Frenking, G.

PY - 2000/12/21

Y1 - 2000/12/21

N2 - A new homoleptic diplatinum complex [Pt2(GaCp*)2(μ2-GaCp*)3] (Cp* = pentamethylcyclopentadienyl) exhibiting a central unit of two platinum atoms coordinated by five Cp*Ga groups acting as terminal as well as bridging ligands, was synthesized by the reaction of tris(ethylene)platinum(0) with an excess of (Cp*Ga)6 and was characterized by structural and quantum chemical methods.

AB - A new homoleptic diplatinum complex [Pt2(GaCp*)2(μ2-GaCp*)3] (Cp* = pentamethylcyclopentadienyl) exhibiting a central unit of two platinum atoms coordinated by five Cp*Ga groups acting as terminal as well as bridging ligands, was synthesized by the reaction of tris(ethylene)platinum(0) with an excess of (Cp*Ga)6 and was characterized by structural and quantum chemical methods.

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M3 - Article

AN - SCOPUS:0034700580

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SP - 2495

EP - 2496

JO - Chemical Communications

JF - Chemical Communications

IS - 24

ER -

[Pt₂(GaCp)₂(μ₂-GaCp)₃]: Structure and bonding situation of the first homoleptic platinum complex with terminal and bridging Cp*Ga ligands

Abstract

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