Pt-Catalyzed D-Glucose Oxidation Reactions for Glucose Fuel Cells

Ji Huang; Philipp Simons; Yusuke Sunada; Jennifer L.M. Rupp; Shunsuke Yagi

doi:10.1149/1945-7111/ac0949

Pt-Catalyzed D-Glucose Oxidation Reactions for Glucose Fuel Cells

Ji Huang, Philipp Simons, Yusuke Sunada, Jennifer L.M. Rupp, Shunsuke Yagi

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

The Pt-catalyzed D-glucose oxidation reaction in neutral electrolytes was investigated for implantable power applications. A reaction mechanism involving two possible oxidation pathways, namely direct and OHads-mediated oxidation, was proposed based on the mass change during electrochemical measurement. PtPd and Pt2Pd were synthesized as anodic catalysts by a solvothermal method, and single-chamber glucose-air fuel cells using a neutral aqueous electrolyte were prototyped successfully. Higher fuel cell performance was achieved with the PtPd catalyst, with a maximum power density of 27.6 μW cm-2 and open-circuit voltage of 0.616 V. Collectively, the present study contributes to maximize the performance of glucose fuel cells.

Original language	English
Article number	064511
Journal	Journal of the Electrochemical Society
Volume	168
Issue number	6
DOIs	https://doi.org/10.1149/1945-7111/ac0949
State	Published - Jun 2021
Externally published	Yes

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title = "Pt-Catalyzed D-Glucose Oxidation Reactions for Glucose Fuel Cells",

abstract = "The Pt-catalyzed D-glucose oxidation reaction in neutral electrolytes was investigated for implantable power applications. A reaction mechanism involving two possible oxidation pathways, namely direct and OHads-mediated oxidation, was proposed based on the mass change during electrochemical measurement. PtPd and Pt2Pd were synthesized as anodic catalysts by a solvothermal method, and single-chamber glucose-air fuel cells using a neutral aqueous electrolyte were prototyped successfully. Higher fuel cell performance was achieved with the PtPd catalyst, with a maximum power density of 27.6 μW cm-2 and open-circuit voltage of 0.616 V. Collectively, the present study contributes to maximize the performance of glucose fuel cells.",

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AU - Huang, Ji

AU - Simons, Philipp

AU - Sunada, Yusuke

AU - Rupp, Jennifer L.M.

AU - Yagi, Shunsuke

PY - 2021/6

Y1 - 2021/6

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AB - The Pt-catalyzed D-glucose oxidation reaction in neutral electrolytes was investigated for implantable power applications. A reaction mechanism involving two possible oxidation pathways, namely direct and OHads-mediated oxidation, was proposed based on the mass change during electrochemical measurement. PtPd and Pt2Pd were synthesized as anodic catalysts by a solvothermal method, and single-chamber glucose-air fuel cells using a neutral aqueous electrolyte were prototyped successfully. Higher fuel cell performance was achieved with the PtPd catalyst, with a maximum power density of 27.6 μW cm-2 and open-circuit voltage of 0.616 V. Collectively, the present study contributes to maximize the performance of glucose fuel cells.

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ER -

Pt-Catalyzed D-Glucose Oxidation Reactions for Glucose Fuel Cells

Abstract

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