TY - JOUR
T1 - Pseudorotation and the environmental effects of the phosphorescence lifetime of benzene
AU - Fischer, S.
N1 - Funding Information:
The authorw ou!d.like to thankP rofessor E.W. Schlagw ho pointed out this prob1e.mto him. Furthermore,h e andD r. Schneiderh elpedw ith manyi nspir-ing discus~on.s. This work wass upportedb y a grant from the MaterialsR esearchC entera t Northwestern University.
PY - 1971/8/15
Y1 - 1971/8/15
N2 - The strong temperature dependence of the phosphorescent decay rate of benzene is attributed to pseudorotational motion of benzene which has the lowered D2h symmetry in the triplet state. This model accounts for the unusual deuterium effect of the activation energy, the very large pre-exponential factor, the low onset temperature, and the solvent effects.
AB - The strong temperature dependence of the phosphorescent decay rate of benzene is attributed to pseudorotational motion of benzene which has the lowered D2h symmetry in the triplet state. This model accounts for the unusual deuterium effect of the activation energy, the very large pre-exponential factor, the low onset temperature, and the solvent effects.
UR - http://www.scopus.com/inward/record.url?scp=49649159627&partnerID=8YFLogxK
U2 - 10.1016/0009-2614(71)80318-4
DO - 10.1016/0009-2614(71)80318-4
M3 - Article
AN - SCOPUS:49649159627
SN - 0009-2614
VL - 10
SP - 397
EP - 400
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 4
ER -