Proton transport in solid electrolytes with clathrate structure

Simin Aschrafi-Mahabadi, Marcella Cappadonia, Ulrich Stimming

Research output: Contribution to journalArticlepeer-review

18 Scopus citations

Abstract

The bulk electric conductivity and the static dielectric constant of acid polyhydrates, having a clathrate structure, were determined between 4 and 300 K. The effect of isotopic exchange (D versus H) was investigated in the same temperature range. Protonated and deuterated acids show virtually identical Arrhenius plots of the conductivity between room temperature and 125 K, below that temperature they differ. The deuterated compound exhibits a smaller conductivity and a smaller dielectric constant as compared with the protonated one.

Original languageEnglish
Pages (from-to)311-315
Number of pages5
JournalSolid State Ionics
Volume70-71
Issue numberPART 1
DOIs
StatePublished - 1994
Externally publishedYes

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