Problem of the Structure of Carbodiphosphoranes, R3PCPR3: New Aspects

Hubert Schmidbaur; Georg Hasslberger; Ulrich Deschler; Ulrich Schubert; Charles kappenstein; Albin Frank

doi:10.1002/anie.197904081

Problem of the Structure of Carbodiphosphoranes, R₃PCPR₃: New Aspects

Hubert Schmidbaur
, Georg Hasslberger
, Ulrich Deschler
, Ulrich Schubert
, Charles kappenstein
, Albin Frank

Department of Chemistry

Technical University of Munich
Université de Reims Champagne-Ardenne

Research output: Contribution to journal › Article › peer-review

39 Scopus citations

Abstract

The PCP angle in crystalline carbodiphosphoranes and the triboluminescence shown by some modifications, e.g. of Ph₃PCPPH₃ have been thought to be related for some time. The search for further outstanding structural features has now led to a deeper understanding of this phenomenon and also showed that the bonding in MePh₂PCPPh₂Me is far better explained in terms of the polar A than by the nonpolar from B. (Figure Presented.)

Original language	English
Pages (from-to)	408-409
Number of pages	2
Journal	Angewandte Chemie International Edition in English
Volume	18
Issue number	5
DOIs	https://doi.org/10.1002/anie.197904081
State	Published - May 1979

Access to Document

10.1002/anie.197904081

Cite this

@article{87220b39d9d84ac9a672ba71ceb10c35,

title = "Problem of the Structure of Carbodiphosphoranes, R3PCPR3: New Aspects",

abstract = "The PCP angle in crystalline carbodiphosphoranes and the triboluminescence shown by some modifications, e.g. of Ph3PCPPH3 have been thought to be related for some time. The search for further outstanding structural features has now led to a deeper understanding of this phenomenon and also showed that the bonding in MePh2PCPPh2Me is far better explained in terms of the polar A than by the nonpolar from B. (Figure Presented.)",

author = "Hubert Schmidbaur and Georg Hasslberger and Ulrich Deschler and Ulrich Schubert and Charles kappenstein and Albin Frank",

year = "1979",

month = may,

doi = "10.1002/anie.197904081",

language = "English",

volume = "18",

pages = "408--409",

journal = "Angewandte Chemie International Edition in English",

issn = "0570-0833",

publisher = "John Wiley and Sons Inc.",

number = "5",

}

TY - JOUR

T1 - Problem of the Structure of Carbodiphosphoranes, R3PCPR3

T2 - New Aspects

AU - Schmidbaur, Hubert

AU - Hasslberger, Georg

AU - Deschler, Ulrich

AU - Schubert, Ulrich

AU - kappenstein, Charles

AU - Frank, Albin

PY - 1979/5

Y1 - 1979/5

N2 - The PCP angle in crystalline carbodiphosphoranes and the triboluminescence shown by some modifications, e.g. of Ph3PCPPH3 have been thought to be related for some time. The search for further outstanding structural features has now led to a deeper understanding of this phenomenon and also showed that the bonding in MePh2PCPPh2Me is far better explained in terms of the polar A than by the nonpolar from B. (Figure Presented.)

AB - The PCP angle in crystalline carbodiphosphoranes and the triboluminescence shown by some modifications, e.g. of Ph3PCPPH3 have been thought to be related for some time. The search for further outstanding structural features has now led to a deeper understanding of this phenomenon and also showed that the bonding in MePh2PCPPh2Me is far better explained in terms of the polar A than by the nonpolar from B. (Figure Presented.)

UR - https://www.scopus.com/pages/publications/84985556731

U2 - 10.1002/anie.197904081

DO - 10.1002/anie.197904081

M3 - Article

AN - SCOPUS:84985556731

SN - 0570-0833

VL - 18

SP - 408

EP - 409

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 5

ER -

Problem of the Structure of Carbodiphosphoranes, R₃PCPR₃: New Aspects

Abstract

Access to Document

Other files and links

Fingerprint

Cite this