TY - JOUR
T1 - Problem of the Structure of Carbodiphosphoranes, R3PCPR3
T2 - New Aspects
AU - Schmidbaur, Hubert
AU - Hasslberger, Georg
AU - Deschler, Ulrich
AU - Schubert, Ulrich
AU - kappenstein, Charles
AU - Frank, Albin
PY - 1979/5
Y1 - 1979/5
N2 - The PCP angle in crystalline carbodiphosphoranes and the triboluminescence shown by some modifications, e.g. of Ph3PCPPH3 have been thought to be related for some time. The search for further outstanding structural features has now led to a deeper understanding of this phenomenon and also showed that the bonding in MePh2PCPPh2Me is far better explained in terms of the polar A than by the nonpolar from B. (Figure Presented.)
AB - The PCP angle in crystalline carbodiphosphoranes and the triboluminescence shown by some modifications, e.g. of Ph3PCPPH3 have been thought to be related for some time. The search for further outstanding structural features has now led to a deeper understanding of this phenomenon and also showed that the bonding in MePh2PCPPh2Me is far better explained in terms of the polar A than by the nonpolar from B. (Figure Presented.)
UR - http://www.scopus.com/inward/record.url?scp=84985556731&partnerID=8YFLogxK
U2 - 10.1002/anie.197904081
DO - 10.1002/anie.197904081
M3 - Article
AN - SCOPUS:84985556731
SN - 0570-0833
VL - 18
SP - 408
EP - 409
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 5
ER -