Problem of the Structure of Carbodiphosphoranes, R3PCPR3: New Aspects

Hubert Schmidbaur, Georg Hasslberger, Ulrich Deschler, Ulrich Schubert, Charles kappenstein, Albin Frank

Research output: Contribution to journalArticlepeer-review

38 Scopus citations

Abstract

The PCP angle in crystalline carbodiphosphoranes and the triboluminescence shown by some modifications, e.g. of Ph3PCPPH3 have been thought to be related for some time. The search for further outstanding structural features has now led to a deeper understanding of this phenomenon and also showed that the bonding in MePh2PCPPh2Me is far better explained in terms of the polar A than by the nonpolar from B. (Figure Presented.)

Original languageEnglish
Pages (from-to)408-409
Number of pages2
JournalAngewandte Chemie International Edition in English
Volume18
Issue number5
DOIs
StatePublished - May 1979
Externally publishedYes

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