Preparation of a Pt-Ru/C catalyst from carbonyl complexes for fuel cell applications

A. J. Dickinson, L. P.L. Carrette, J. A. Collins, K. A. Friedrich, U. Stimming

Research output: Contribution to journalArticlepeer-review

127 Scopus citations

Abstract

A new method for producing highly active, carbon supported, Pt-Ru catalysts for methanol oxidation is presented. The catalyst is produced from carbonyl metal complexes by deposition of the precursors on carbon in a high boiling-point solvent, and a simple method of producing the necessary Pt carbonyl complex is also reported. Well distributed PtRu catalysts with high dispersion and narrow size distribution are obtained. Comparison of the catalyst produced by this method against commercial and in-house sulphito route catalysts show that it has a promising activity as well as presenting an easier route to ternary and quaternary catalysts.

Original languageEnglish
Pages (from-to)3733-3739
Number of pages7
JournalElectrochimica Acta
Volume47
Issue number22-23
DOIs
StatePublished - 30 Aug 2002

Keywords

  • Direct methanol fuel cell
  • Fuel cell catalysts
  • Membrane electrode assembly
  • Methanol electrooxidation
  • Platinum, ruthenium, polymer electrolyte membranes

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