Preparation and properties of cyano(triphenylphosphoniomethanide)-gold(I) and its oxidative-addition products with halogens

Graham A. Bowmaker; Hubert Schmidbaur

doi:10.1039/DT9840002859

Preparation and properties of cyano(triphenylphosphoniomethanide)-gold(I) and its oxidative-addition products with halogens

Graham A. Bowmaker, Hubert Schmidbaur

Department of Chemistry

University of Auckland

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

The 1:1 complex [Au(CN)(CH₂PPh₃)] has been obtained from the reaction between triphenylphosphoniomethanide and gold(I) cyanide. This undergoes oxidative-addition reactions with halogens X₂ to give the gold(III) complexes trans-[AuX₂(CN)(CH₂PPh₃)]. The complexes have been characterized by conductivity measurements, n.m.r., and vibrational spectroscopy, and contain a stable bond between the ylidic carbon and the gold atom.

Original language	English
Pages (from-to)	2859-2861
Number of pages	3
Journal	Journal of the Chemical Society. Dalton Transactions
Issue number	12
DOIs	https://doi.org/10.1039/DT9840002859
State	Published - 1984

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title = "Preparation and properties of cyano(triphenylphosphoniomethanide)-gold(I) and its oxidative-addition products with halogens",

abstract = "The 1:1 complex [Au(CN)(CH2PPh3)] has been obtained from the reaction between triphenylphosphoniomethanide and gold(I) cyanide. This undergoes oxidative-addition reactions with halogens X2 to give the gold(III) complexes trans-[AuX2(CN)(CH2PPh3)]. The complexes have been characterized by conductivity measurements, n.m.r., and vibrational spectroscopy, and contain a stable bond between the ylidic carbon and the gold atom.",

author = "Bowmaker, {Graham A.} and Hubert Schmidbaur",

year = "1984",

doi = "10.1039/DT9840002859",

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journal = "Journal of the Chemical Society. Dalton Transactions",

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T1 - Preparation and properties of cyano(triphenylphosphoniomethanide)-gold(I) and its oxidative-addition products with halogens

AU - Bowmaker, Graham A.

AU - Schmidbaur, Hubert

PY - 1984

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N2 - The 1:1 complex [Au(CN)(CH2PPh3)] has been obtained from the reaction between triphenylphosphoniomethanide and gold(I) cyanide. This undergoes oxidative-addition reactions with halogens X2 to give the gold(III) complexes trans-[AuX2(CN)(CH2PPh3)]. The complexes have been characterized by conductivity measurements, n.m.r., and vibrational spectroscopy, and contain a stable bond between the ylidic carbon and the gold atom.

AB - The 1:1 complex [Au(CN)(CH2PPh3)] has been obtained from the reaction between triphenylphosphoniomethanide and gold(I) cyanide. This undergoes oxidative-addition reactions with halogens X2 to give the gold(III) complexes trans-[AuX2(CN)(CH2PPh3)]. The complexes have been characterized by conductivity measurements, n.m.r., and vibrational spectroscopy, and contain a stable bond between the ylidic carbon and the gold atom.

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DO - 10.1039/DT9840002859

M3 - Article

AN - SCOPUS:37049102238

SN - 1472-7773

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JO - Journal of the Chemical Society. Dalton Transactions

JF - Journal of the Chemical Society. Dalton Transactions

IS - 12

ER -

Preparation and properties of cyano(triphenylphosphoniomethanide)-gold(I) and its oxidative-addition products with halogens

Abstract

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