Preparation and crystal structure of Li4[TaN3]

R. Niewa; D. A. Zherebtsov; H. Borrmann; R. Kniep

doi:10.1002/1521-3749(200211)628:11<2505::AID-ZAAC2505>3.0.CO;2-S

Preparation and crystal structure of Li₄[TaN₃]

R. Niewa, D. A. Zherebtsov, H. Borrmann, R. Kniep

Max Planck Institute for Chemical Physics of Solids

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

The new lithium nitridotantalate(V), Li₄[TaN₃], was prepared by reaction of Li₁₅[CrN₄]₂N with the wall of a welded Ta ampoule in the presence of metallic Li at 1470 K. Li₄[TaN₃] forms colourless single crystals (platelets, space group Ibca, No. 73, a = 491.85(4) pm, b = 973.59(6) pm, c = 1415.0(1) pm, Z = 8, R1 = 0.0288). The crystal structure is described as Li₂O superstructure with ordered occupation of the tetrahedral sites by Li and Ta. The resulting arrangement leads to infinite chains _∞¹[TaN₂N_2/2^4- running along [100].

Original language	English
Pages (from-to)	2505-2508
Number of pages	4
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	628
Issue number	11
DOIs	https://doi.org/10.1002/1521-3749(200211)628:11<2505::AID-ZAAC2505>3.0.CO;2-S
State	Published - 2002
Externally published	Yes

Keywords

Crystal structure
Lithium
Nitrides
Tantalum

Access to Document

10.1002/1521-3749(200211)628:11<2505::AID-ZAAC2505>3.0.CO;2-S

Cite this

@article{7a1663d7744543ab98c76c904ab8a760,

title = "Preparation and crystal structure of Li4[TaN3]",

abstract = "The new lithium nitridotantalate(V), Li4[TaN3], was prepared by reaction of Li15[CrN4]2N with the wall of a welded Ta ampoule in the presence of metallic Li at 1470 K. Li4[TaN3] forms colourless single crystals (platelets, space group Ibca, No. 73, a = 491.85(4) pm, b = 973.59(6) pm, c = 1415.0(1) pm, Z = 8, R1 = 0.0288). The crystal structure is described as Li2O superstructure with ordered occupation of the tetrahedral sites by Li and Ta. The resulting arrangement leads to infinite chains ∞1[TaN2N2/24- running along [100].",

keywords = "Crystal structure, Lithium, Nitrides, Tantalum",

author = "R. Niewa and Zherebtsov, {D. A.} and H. Borrmann and R. Kniep",

year = "2002",

doi = "10.1002/1521-3749(200211)628:11<2505::AID-ZAAC2505>3.0.CO;2-S",

language = "English",

volume = "628",

pages = "2505--2508",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

publisher = "Wiley-VCH Verlag",

number = "11",

}

TY - JOUR

T1 - Preparation and crystal structure of Li4[TaN3]

AU - Niewa, R.

AU - Zherebtsov, D. A.

AU - Borrmann, H.

AU - Kniep, R.

PY - 2002

Y1 - 2002

N2 - The new lithium nitridotantalate(V), Li4[TaN3], was prepared by reaction of Li15[CrN4]2N with the wall of a welded Ta ampoule in the presence of metallic Li at 1470 K. Li4[TaN3] forms colourless single crystals (platelets, space group Ibca, No. 73, a = 491.85(4) pm, b = 973.59(6) pm, c = 1415.0(1) pm, Z = 8, R1 = 0.0288). The crystal structure is described as Li2O superstructure with ordered occupation of the tetrahedral sites by Li and Ta. The resulting arrangement leads to infinite chains ∞1[TaN2N2/24- running along [100].

AB - The new lithium nitridotantalate(V), Li4[TaN3], was prepared by reaction of Li15[CrN4]2N with the wall of a welded Ta ampoule in the presence of metallic Li at 1470 K. Li4[TaN3] forms colourless single crystals (platelets, space group Ibca, No. 73, a = 491.85(4) pm, b = 973.59(6) pm, c = 1415.0(1) pm, Z = 8, R1 = 0.0288). The crystal structure is described as Li2O superstructure with ordered occupation of the tetrahedral sites by Li and Ta. The resulting arrangement leads to infinite chains ∞1[TaN2N2/24- running along [100].

KW - Crystal structure

KW - Lithium

KW - Nitrides

KW - Tantalum

UR - http://www.scopus.com/inward/record.url?scp=0036035280&partnerID=8YFLogxK

U2 - 10.1002/1521-3749(200211)628:11<2505::AID-ZAAC2505>3.0.CO;2-S

DO - 10.1002/1521-3749(200211)628:11<2505::AID-ZAAC2505>3.0.CO;2-S

M3 - Article

AN - SCOPUS:0036035280

SN - 0044-2313

VL - 628

SP - 2505

EP - 2508

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 11

ER -

Preparation and crystal structure of Li₄[TaN₃]

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this