Preparation and characterization of homo- and co-polymers of some vinyl monomers via ATRP by using imine macrocycle as ligand

A. Amin, M. H. Ayoub, M. Abd El-Ghaffar, B. Rieger

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

Imine macrocyclic ligand M1 was involved in homo- and co-polymerization of some vinyl monomers via atom transfer radical polymerization technique (ATRP). Hereby, vinyl acetate, styrene and methyl acrylate monomers were homopolymerized. On the other hand, they were involved in copolymerization with MMA. M1: CuBr: initiator: monomer percentages were 1:2:4:400. 1HNMR confirmed the structures of the resulting polymers. The thermal behaviors of some selected polymers were studied.

Original languageEnglish
Pages (from-to)1329-1338
Number of pages10
JournalJournal of Macromolecular Science - Pure and Applied Chemistry
Volume42 A
Issue number10
DOIs
StatePublished - Oct 2005
Externally publishedYes

Keywords

  • ATRP
  • Copolymers
  • Homopolymers
  • Imine macrocycles
  • Thermal analyses

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