Practical synthesis of new and highly efficient ligands for the Suzuki reaction of aryl chlorides

Alexander Zapf, Ralf Jackstell, Franck Rataboul, Thomas Riermeier, Axel Monsees, Christa Fuhrmann, Nadim Shaikh, Uwe Dingerdissen, Matthias Beller

Research output: Contribution to journalArticlepeer-review

245 Scopus citations

Abstract

A practical synthesis of a novel class of phosphine ligands, phosphino substituted N-aryl pyrroles (PAP ligands), has been developed. These ligands are applied in the palladium-catalyzed coupling of a variety of aryl and heteroaryl chlorides with phenylboronic acid showing exceedingly high turnover numbers at mild reaction temperatures and even at room temperature.

Original languageEnglish
Pages (from-to)38-39
Number of pages2
JournalChemical Communications
Volume4
Issue number1
DOIs
StatePublished - 2004
Externally publishedYes

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