Polyspirocyclische Komplexe des Palladiums mit Phosphor‐Yliden

Hubert Schmidbaur, Hans Peter Scherm

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Abstract

Polyspirocyclic Complexes of Palladium with Phosphorus Ylides Bis(trimethylphosphine)palladium(II) chloride reacts with trimethyl(methylene)phosphorane, 1‐methyl‐1‐methylene‐λ5‐phospholane and ‐phosphorinane to form polyspirocyclic dimers of the general formula {R2P(CH2)2Pd‐μ,μ′‐[R2P(CH2)2]2‐Pd(CH2)2PR2}, R2 =(CH3)2, [CH2]4 and [CH2]5 (3–5). With (CH3)3 PCH2 an ionic precursor {(CH3)2P(CH2)2Pd[CH2P‐(CH3)3]2}⊕Cl⊖ (2) has been detected.

Original languageGerman
Pages (from-to)797-800
Number of pages4
JournalChemische Berichte
Volume111
Issue number2
DOIs
StatePublished - 1978
Externally publishedYes

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