Polygold(1-adamantyl)ammonium salts

José M. López-de-Luzuriaga, Annette Schier, Hubert Schmidbaur

Research output: Contribution to journalArticlepeer-review

12 Scopus citations

Abstract

The reaction of 1-adamantylamine with tris(triphenylphosphaneauriojoxonium tetrafluoroborate results in the formation of the trinuclear adamantyltrisftriphenylphosphaneaurio)ammonium tetrafluoroborate (C10H15N[Au(PPh3)]3) +BF4-. The product can be further aurated by addition of equimolar amounts of triphenylphosphanegold(I) tetrafluoroborate to give the tetranuclear complex (C10H15N[Au(PPh3)]4) 2+{BF4-)2. Both compounds have been fully characterized by analytical and spectroscopic data, and in the case of the trinuclear complex by a single crystal X-ray structure determination.

Original languageEnglish
Pages (from-to)221-223
Number of pages3
JournalChemische Berichte
Volume130
Issue number2
DOIs
StatePublished - 1997
Externally publishedYes

Keywords

  • (1-Adamantyl)ammonium salts
  • Gold
  • Polygoldammonium salts
  • Tetranuclear complex
  • Trinuclear complex, X-cay structure of

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