Plasmachemical synthesis of the binary hexafluorides of Mo, Os, Ir, Te, and U

T. Chemnitz; M. R. Buchner; W. Petry; F. Kraus

doi:10.1016/j.jfluchem.2021.109862

Plasmachemical synthesis of the binary hexafluorides of Mo, Os, Ir, Te, and U

T. Chemnitz, M. R. Buchner, W. Petry, F. Kraus

Department of Physics

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Starting from the respective metal, we have synthesized the binary hexafluorides MF₆ of M = Mo, Os, Ir, Te, and U by the use of a remote fluorine plasma source using a mixture of Ar and NF₃ as the feed gas. The formation of the binary hexafluorides was confirmed by several different spectroscopic methods including IR, Raman, UV/VIS, and NMR spectroscopy.

Original language	English
Article number	109862
Journal	Journal of Fluorine Chemistry
Volume	249
DOIs	https://doi.org/10.1016/j.jfluchem.2021.109862
State	Published - Sep 2021

Keywords

Fluorine
Hexafluoride
Plasma
Platinum metal

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10.1016/j.jfluchem.2021.109862

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title = "Plasmachemical synthesis of the binary hexafluorides of Mo, Os, Ir, Te, and U",

abstract = "Starting from the respective metal, we have synthesized the binary hexafluorides MF6 of M = Mo, Os, Ir, Te, and U by the use of a remote fluorine plasma source using a mixture of Ar and NF3 as the feed gas. The formation of the binary hexafluorides was confirmed by several different spectroscopic methods including IR, Raman, UV/VIS, and NMR spectroscopy.",

keywords = "Fluorine, Hexafluoride, Plasma, Platinum metal",

author = "T. Chemnitz and Buchner, {M. R.} and W. Petry and F. Kraus",

note = "Publisher Copyright: {\textcopyright} 2021 Elsevier B.V.",

year = "2021",

month = sep,

doi = "10.1016/j.jfluchem.2021.109862",

language = "English",

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journal = "Journal of Fluorine Chemistry",

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T1 - Plasmachemical synthesis of the binary hexafluorides of Mo, Os, Ir, Te, and U

AU - Chemnitz, T.

AU - Buchner, M. R.

AU - Petry, W.

AU - Kraus, F.

PY - 2021/9

Y1 - 2021/9

N2 - Starting from the respective metal, we have synthesized the binary hexafluorides MF6 of M = Mo, Os, Ir, Te, and U by the use of a remote fluorine plasma source using a mixture of Ar and NF3 as the feed gas. The formation of the binary hexafluorides was confirmed by several different spectroscopic methods including IR, Raman, UV/VIS, and NMR spectroscopy.

AB - Starting from the respective metal, we have synthesized the binary hexafluorides MF6 of M = Mo, Os, Ir, Te, and U by the use of a remote fluorine plasma source using a mixture of Ar and NF3 as the feed gas. The formation of the binary hexafluorides was confirmed by several different spectroscopic methods including IR, Raman, UV/VIS, and NMR spectroscopy.

KW - Fluorine

KW - Hexafluoride

KW - Plasma

KW - Platinum metal

UR - http://www.scopus.com/inward/record.url?scp=85111960568&partnerID=8YFLogxK

U2 - 10.1016/j.jfluchem.2021.109862

DO - 10.1016/j.jfluchem.2021.109862

M3 - Article

AN - SCOPUS:85111960568

SN - 0022-1139

VL - 249

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

M1 - 109862

ER -

Plasmachemical synthesis of the binary hexafluorides of Mo, Os, Ir, Te, and U

Abstract

Keywords

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