Photoredox capacity expanded by the Cu site of CuFe-Mabiq

Matthias Huber; Ajeet Kumar; Jürgen Hauer; Erling Thyrhaug; Corinna R. Hess

doi:10.1039/d4cc06104g

Photoredox capacity expanded by the Cu site of CuFe-Mabiq

Matthias Huber
, Ajeet Kumar
, Jürgen Hauer
, Erling Thyrhaug
, Corinna R. Hess

Research output: Contribution to journal › Article › peer-review

Abstract

The monometallic Fe-Mabiq and bimetallic CuFe-Mabiq photoredox catalysts feature similar optical spectra and short excited-state lifetimes. Nevertheless, they exhibit markedly different photochemistry. Photoreduction proceeds significantly faster for the bimetallic complex, and uniquely generates the three-electron reduced form. These characteristics underpin the self-sensitized photocatalytic behaviour of the bimetallic complex.

Original language	English
Pages (from-to)	5731-5734
Number of pages	4
Journal	Chemical Communications
Volume	61
Issue number	31
DOIs	https://doi.org/10.1039/d4cc06104g
State	Published - 25 Feb 2025

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10.1039/d4cc06104g

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title = "Photoredox capacity expanded by the Cu site of CuFe-Mabiq",

abstract = "The monometallic Fe-Mabiq and bimetallic CuFe-Mabiq photoredox catalysts feature similar optical spectra and short excited-state lifetimes. Nevertheless, they exhibit markedly different photochemistry. Photoreduction proceeds significantly faster for the bimetallic complex, and uniquely generates the three-electron reduced form. These characteristics underpin the self-sensitized photocatalytic behaviour of the bimetallic complex.",

author = "Matthias Huber and Ajeet Kumar and J{\"u}rgen Hauer and Erling Thyrhaug and Hess, \{Corinna R.\}",

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AU - Huber, Matthias

AU - Kumar, Ajeet

AU - Hauer, Jürgen

AU - Thyrhaug, Erling

AU - Hess, Corinna R.

PY - 2025/2/25

Y1 - 2025/2/25

N2 - The monometallic Fe-Mabiq and bimetallic CuFe-Mabiq photoredox catalysts feature similar optical spectra and short excited-state lifetimes. Nevertheless, they exhibit markedly different photochemistry. Photoreduction proceeds significantly faster for the bimetallic complex, and uniquely generates the three-electron reduced form. These characteristics underpin the self-sensitized photocatalytic behaviour of the bimetallic complex.

AB - The monometallic Fe-Mabiq and bimetallic CuFe-Mabiq photoredox catalysts feature similar optical spectra and short excited-state lifetimes. Nevertheless, they exhibit markedly different photochemistry. Photoreduction proceeds significantly faster for the bimetallic complex, and uniquely generates the three-electron reduced form. These characteristics underpin the self-sensitized photocatalytic behaviour of the bimetallic complex.

UR - https://www.scopus.com/pages/publications/85219570876

U2 - 10.1039/d4cc06104g

DO - 10.1039/d4cc06104g

M3 - Article

AN - SCOPUS:85219570876

SN - 1359-7345

VL - 61

SP - 5731

EP - 5734

JO - Chemical Communications

JF - Chemical Communications

IS - 31

ER -

Photoredox capacity expanded by the Cu site of CuFe-Mabiq

Abstract

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