Photoredox capacity expanded by the Cu site of CuFe-Mabiq

Matthias Huber; Ajeet Kumar; Jürgen Hauer; Erling Thyrhaug; Corinna R. Hess

doi:10.1039/d4cc06104g

Photoredox capacity expanded by the Cu site of CuFe-Mabiq

Matthias Huber, Ajeet Kumar, Jürgen Hauer, Erling Thyrhaug, Corinna R. Hess

Research output: Contribution to journal › Article › peer-review

Abstract

The monometallic Fe-Mabiq and bimetallic CuFe-Mabiq photoredox catalysts feature similar optical spectra and short excited-state lifetimes. Nevertheless, they exhibit markedly different photochemistry. Photoreduction proceeds significantly faster for the bimetallic complex, and uniquely generates the three-electron reduced form. These characteristics underpin the self-sensitized photocatalytic behaviour of the bimetallic complex.

Original language	English
Journal	Chemical Communications
DOIs	https://doi.org/10.1039/d4cc06104g
State	Accepted/In press - 2025

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title = "Photoredox capacity expanded by the Cu site of CuFe-Mabiq",

abstract = "The monometallic Fe-Mabiq and bimetallic CuFe-Mabiq photoredox catalysts feature similar optical spectra and short excited-state lifetimes. Nevertheless, they exhibit markedly different photochemistry. Photoreduction proceeds significantly faster for the bimetallic complex, and uniquely generates the three-electron reduced form. These characteristics underpin the self-sensitized photocatalytic behaviour of the bimetallic complex.",

author = "Matthias Huber and Ajeet Kumar and J{\"u}rgen Hauer and Erling Thyrhaug and Hess, {Corinna R.}",

note = "Publisher Copyright: {\textcopyright} 2025 The Royal Society of Chemistry.",

year = "2025",

doi = "10.1039/d4cc06104g",

language = "English",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - Photoredox capacity expanded by the Cu site of CuFe-Mabiq

AU - Huber, Matthias

AU - Kumar, Ajeet

AU - Hauer, Jürgen

AU - Thyrhaug, Erling

AU - Hess, Corinna R.

PY - 2025

Y1 - 2025

N2 - The monometallic Fe-Mabiq and bimetallic CuFe-Mabiq photoredox catalysts feature similar optical spectra and short excited-state lifetimes. Nevertheless, they exhibit markedly different photochemistry. Photoreduction proceeds significantly faster for the bimetallic complex, and uniquely generates the three-electron reduced form. These characteristics underpin the self-sensitized photocatalytic behaviour of the bimetallic complex.

AB - The monometallic Fe-Mabiq and bimetallic CuFe-Mabiq photoredox catalysts feature similar optical spectra and short excited-state lifetimes. Nevertheless, they exhibit markedly different photochemistry. Photoreduction proceeds significantly faster for the bimetallic complex, and uniquely generates the three-electron reduced form. These characteristics underpin the self-sensitized photocatalytic behaviour of the bimetallic complex.

UR - http://www.scopus.com/inward/record.url?scp=85219570876&partnerID=8YFLogxK

U2 - 10.1039/d4cc06104g

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M3 - Article

AN - SCOPUS:85219570876

SN - 1359-7345

JO - Chemical Communications

JF - Chemical Communications

ER -

Photoredox capacity expanded by the Cu site of CuFe-Mabiq

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