Photolytic and radiolytic radical formation in allylacetate

A. Tiesler; H. Zott; H. Heusinger

doi:10.1016/0146-5724(81)90263-6

Photolytic and radiolytic radical formation in allylacetate

A. Tiesler, H. Zott, H. Heusinger

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Technical University of Munich

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Abstract

Radiolysis of allylacetate at - 196°C produces two types of allyl radicals CH₂CHCH₂^., {A figure is presented}. By photobleaching with visible light these radicals decompose and methyl radicals appear. In photolysis, sensitized by N-ethylmaleimide, methyl radicals and traces of allyl- and acyl-radicals are observed. A mechanism for radical formation is proposed.

Original language	English
Pages (from-to)	141-144
Number of pages	4
Journal	Radiation Physics and Chemistry
Volume	17
Issue number	3
DOIs	https://doi.org/10.1016/0146-5724(81)90263-6
State	Published - 1981

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@article{79d03c94affe437a887e01d38b1f8d1e,

title = "Photolytic and radiolytic radical formation in allylacetate",

abstract = "Radiolysis of allylacetate at - 196°C produces two types of allyl radicals CH2CHCH2., {A figure is presented}. By photobleaching with visible light these radicals decompose and methyl radicals appear. In photolysis, sensitized by N-ethylmaleimide, methyl radicals and traces of allyl- and acyl-radicals are observed. A mechanism for radical formation is proposed.",

author = "A. Tiesler and H. Zott and H. Heusinger",

year = "1981",

doi = "10.1016/0146-5724(81)90263-6",

language = "English",

volume = "17",

pages = "141--144",

journal = "Radiation Physics and Chemistry",

issn = "0146-5724",

publisher = "Elsevier BV",

number = "3",

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TY - JOUR

T1 - Photolytic and radiolytic radical formation in allylacetate

AU - Tiesler, A.

AU - Zott, H.

AU - Heusinger, H.

PY - 1981

Y1 - 1981

N2 - Radiolysis of allylacetate at - 196°C produces two types of allyl radicals CH2CHCH2., {A figure is presented}. By photobleaching with visible light these radicals decompose and methyl radicals appear. In photolysis, sensitized by N-ethylmaleimide, methyl radicals and traces of allyl- and acyl-radicals are observed. A mechanism for radical formation is proposed.

AB - Radiolysis of allylacetate at - 196°C produces two types of allyl radicals CH2CHCH2., {A figure is presented}. By photobleaching with visible light these radicals decompose and methyl radicals appear. In photolysis, sensitized by N-ethylmaleimide, methyl radicals and traces of allyl- and acyl-radicals are observed. A mechanism for radical formation is proposed.

UR - http://www.scopus.com/inward/record.url?scp=49149135114&partnerID=8YFLogxK

U2 - 10.1016/0146-5724(81)90263-6

DO - 10.1016/0146-5724(81)90263-6

M3 - Article

AN - SCOPUS:49149135114

SN - 0146-5724

VL - 17

SP - 141

EP - 144

JO - Radiation Physics and Chemistry

JF - Radiation Physics and Chemistry

IS - 3

ER -

Photolytic and radiolytic radical formation in allylacetate

Abstract

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