Photoluminescent Cu(i): Vs. Ag(i) complexes: Slowing down emission in Cu(i) complexes by pentacoordinate low-lying excited states

José M. Carbonell-Vilar; Elisa Fresta; Donatella Armentano; Rubén D. Costa; Marta Viciano-Chumillas; Joan Cano

doi:10.1039/c9dt00772e

Photoluminescent Cu(i): Vs. Ag(i) complexes: Slowing down emission in Cu(i) complexes by pentacoordinate low-lying excited states

José M. Carbonell-Vilar
, Elisa Fresta
, Donatella Armentano
, Rubén D. Costa
, Marta Viciano-Chumillas
, Joan Cano

University of Valencia
IMDEA Materials Institute
Universidad Autónoma de Madrid
Universite della Calabria

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

This work describes the synthesis, and structural, spectroscopic, and theoretical studies of a mononuclear silver(i) complex with the formula [Ag(Xantphos)(4,4′-(MeO)₂-2,2′-bipy)]BF₄·DCM (1·BF₄) [Xantphos: 4,5-bis(diphenylphosphino)-9,9′-dimethylxanthene]. We provide meaningful insights into the enhancement of the photoluminescence features of this silver(i) complex compared to its copper(i) analogue.

Original language	English
Pages (from-to)	9765-9775
Number of pages	11
Journal	Dalton Transactions
Volume	48
Issue number	26
DOIs	https://doi.org/10.1039/c9dt00772e
State	Published - 2019
Externally published	Yes

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title = "Photoluminescent Cu(i): Vs. Ag(i) complexes: Slowing down emission in Cu(i) complexes by pentacoordinate low-lying excited states",

abstract = "This work describes the synthesis, and structural, spectroscopic, and theoretical studies of a mononuclear silver(i) complex with the formula [Ag(Xantphos)(4,4′-(MeO)2-2,2′-bipy)]BF4·DCM (1·BF4) [Xantphos: 4,5-bis(diphenylphosphino)-9,9′-dimethylxanthene]. We provide meaningful insights into the enhancement of the photoluminescence features of this silver(i) complex compared to its copper(i) analogue.",

author = "Carbonell-Vilar, \{Jos{\'e} M.\} and Elisa Fresta and Donatella Armentano and Costa, \{Rub{\'e}n D.\} and Marta Viciano-Chumillas and Joan Cano",

note = "Publisher Copyright: {\textcopyright} 2019 The Royal Society of Chemistry.",

year = "2019",

doi = "10.1039/c9dt00772e",

language = "English",

volume = "48",

pages = "9765--9775",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "26",

}

TY - JOUR

T1 - Photoluminescent Cu(i)

T2 - Vs. Ag(i) complexes: Slowing down emission in Cu(i) complexes by pentacoordinate low-lying excited states

AU - Carbonell-Vilar, José M.

AU - Fresta, Elisa

AU - Armentano, Donatella

AU - Costa, Rubén D.

AU - Viciano-Chumillas, Marta

AU - Cano, Joan

PY - 2019

Y1 - 2019

N2 - This work describes the synthesis, and structural, spectroscopic, and theoretical studies of a mononuclear silver(i) complex with the formula [Ag(Xantphos)(4,4′-(MeO)2-2,2′-bipy)]BF4·DCM (1·BF4) [Xantphos: 4,5-bis(diphenylphosphino)-9,9′-dimethylxanthene]. We provide meaningful insights into the enhancement of the photoluminescence features of this silver(i) complex compared to its copper(i) analogue.

AB - This work describes the synthesis, and structural, spectroscopic, and theoretical studies of a mononuclear silver(i) complex with the formula [Ag(Xantphos)(4,4′-(MeO)2-2,2′-bipy)]BF4·DCM (1·BF4) [Xantphos: 4,5-bis(diphenylphosphino)-9,9′-dimethylxanthene]. We provide meaningful insights into the enhancement of the photoluminescence features of this silver(i) complex compared to its copper(i) analogue.

UR - https://www.scopus.com/pages/publications/85068146748

U2 - 10.1039/c9dt00772e

DO - 10.1039/c9dt00772e

M3 - Article

C2 - 31011739

AN - SCOPUS:85068146748

SN - 1477-9226

VL - 48

SP - 9765

EP - 9775

JO - Dalton Transactions

JF - Dalton Transactions

IS - 26

ER -

Photoluminescent Cu(i): Vs. Ag(i) complexes: Slowing down emission in Cu(i) complexes by pentacoordinate low-lying excited states

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