Photochemistry of Methyltrioxorhenium(VII)

Horst Kunkely; Thomas Türk; Clementina Teixeira; Claude De de Bellefon Meric; Wolfgang Anton Herrmann; Arnd Vogler

doi:10.1021/om00053a003

Photochemistry of Methyltrioxorhenium(VII)

Horst Kunkely, Thomas Türk, Clementina Teixeira, Claude De de Bellefon Meric, Wolfgang Anton Herrmann, Arnd Vogler

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

52 Scopus citations

Abstract

Ligand-to-metal charge transfer excitation of CH₃Re0₃ leads to a homolysis of the CH₃-Re bond. Product formation takes place by outer-sphere back electron transfer or atom abstraction by the methyl radical.

Original language	English
Pages (from-to)	2090-2092
Number of pages	3
Journal	Organometallics
Volume	10
Issue number	7
DOIs	https://doi.org/10.1021/om00053a003
State	Published - 1 Jul 1991

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@article{a0d9e81190c44b4db3efcd751277ac6d,

title = "Photochemistry of Methyltrioxorhenium(VII)",

abstract = "Ligand-to-metal charge transfer excitation of CH3Re03 leads to a homolysis of the CH3-Re bond. Product formation takes place by outer-sphere back electron transfer or atom abstraction by the methyl radical.",

author = "Horst Kunkely and Thomas T{\"u}rk and Clementina Teixeira and {de Bellefon Meric}, {Claude De} and Herrmann, {Wolfgang Anton} and Arnd Vogler",

year = "1991",

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T1 - Photochemistry of Methyltrioxorhenium(VII)

AU - Kunkely, Horst

AU - Türk, Thomas

AU - Teixeira, Clementina

AU - de Bellefon Meric, Claude De

AU - Herrmann, Wolfgang Anton

AU - Vogler, Arnd

PY - 1991/7/1

Y1 - 1991/7/1

N2 - Ligand-to-metal charge transfer excitation of CH3Re03 leads to a homolysis of the CH3-Re bond. Product formation takes place by outer-sphere back electron transfer or atom abstraction by the methyl radical.

AB - Ligand-to-metal charge transfer excitation of CH3Re03 leads to a homolysis of the CH3-Re bond. Product formation takes place by outer-sphere back electron transfer or atom abstraction by the methyl radical.

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U2 - 10.1021/om00053a003

DO - 10.1021/om00053a003

M3 - Article

AN - SCOPUS:0001763801

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VL - 10

SP - 2090

EP - 2092

JO - Organometallics

JF - Organometallics

IS - 7

ER -

Photochemistry of Methyltrioxorhenium(VII)

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