Photochemical processes in 2-fluoroethanol in solid neon

M. Rasanen; J. Murto; V. E. Bondybey

doi:10.1021/j100265a009

Photochemical processes in 2-fluoroethanol in solid neon

M. Rasanen, J. Murto, V. E. Bondybey

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18 Scopus citations

Abstract

FTIR study of 2-fluoroethanol in solid neon shows that, contrary to some previous reports, only the Gg′ and Tt conformers can be trapped. Infrared irradiation in either OH or CH stretching region results in a very efficient conversion of the initially present Gg′ form into the higher energy Tt conformers. The overall isomerization rate is essentially unchanged by deuteration of the OH group.

Original language	English
Pages (from-to)	3967-3970
Number of pages	4
Journal	Journal of Physical Chemistry
Volume	89
Issue number	19
DOIs	https://doi.org/10.1021/j100265a009
State	Published - 1985
Externally published	Yes

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title = "Photochemical processes in 2-fluoroethanol in solid neon",

abstract = "FTIR study of 2-fluoroethanol in solid neon shows that, contrary to some previous reports, only the Gg′ and Tt conformers can be trapped. Infrared irradiation in either OH or CH stretching region results in a very efficient conversion of the initially present Gg′ form into the higher energy Tt conformers. The overall isomerization rate is essentially unchanged by deuteration of the OH group.",

author = "M. Rasanen and J. Murto and Bondybey, {V. E.}",

year = "1985",

doi = "10.1021/j100265a009",

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AU - Rasanen, M.

AU - Murto, J.

AU - Bondybey, V. E.

PY - 1985

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AB - FTIR study of 2-fluoroethanol in solid neon shows that, contrary to some previous reports, only the Gg′ and Tt conformers can be trapped. Infrared irradiation in either OH or CH stretching region results in a very efficient conversion of the initially present Gg′ form into the higher energy Tt conformers. The overall isomerization rate is essentially unchanged by deuteration of the OH group.

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DO - 10.1021/j100265a009

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JO - Journal of Physical Chemistry

JF - Journal of Physical Chemistry

IS - 19

ER -

Photochemical processes in 2-fluoroethanol in solid neon

Abstract

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