Photocatalytic reductive incorporation of carbon dioxide into double bonds

Mark J. Deeprose; Thorsten Bach

doi:10.1039/d5cc00604j

Photocatalytic reductive incorporation of carbon dioxide into double bonds

Mark J. Deeprose
, Thorsten Bach

Chair of Organic Chemistry 1

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

Carbon dioxide (CO₂) is a challenging molecule to incorporate into olefins due to its inherent inert properties. Silanes have now been shown to rapidly react selectively with CO₂, catalysed by the presence of a caesium base, to form formate salts which can undergo a hydrogen atom transfer (HAT) to give the desired CO₂˙⁻ adducts in the presence of activated olefins.

Original language	English
Pages (from-to)	6791-6794
Number of pages	4
Journal	Chemical Communications
Volume	61
Issue number	37
DOIs	https://doi.org/10.1039/d5cc00604j
State	Published - 3 Apr 2025

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title = "Photocatalytic reductive incorporation of carbon dioxide into double bonds",

abstract = "Carbon dioxide (CO2) is a challenging molecule to incorporate into olefins due to its inherent inert properties. Silanes have now been shown to rapidly react selectively with CO2, catalysed by the presence of a caesium base, to form formate salts which can undergo a hydrogen atom transfer (HAT) to give the desired CO2˙− adducts in the presence of activated olefins.",

author = "Deeprose, \{Mark J.\} and Thorsten Bach",

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language = "English",

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AU - Deeprose, Mark J.

AU - Bach, Thorsten

PY - 2025/4/3

Y1 - 2025/4/3

N2 - Carbon dioxide (CO2) is a challenging molecule to incorporate into olefins due to its inherent inert properties. Silanes have now been shown to rapidly react selectively with CO2, catalysed by the presence of a caesium base, to form formate salts which can undergo a hydrogen atom transfer (HAT) to give the desired CO2˙− adducts in the presence of activated olefins.

AB - Carbon dioxide (CO2) is a challenging molecule to incorporate into olefins due to its inherent inert properties. Silanes have now been shown to rapidly react selectively with CO2, catalysed by the presence of a caesium base, to form formate salts which can undergo a hydrogen atom transfer (HAT) to give the desired CO2˙− adducts in the presence of activated olefins.

UR - https://www.scopus.com/pages/publications/105002369095

U2 - 10.1039/d5cc00604j

DO - 10.1039/d5cc00604j

M3 - Article

AN - SCOPUS:105002369095

SN - 1359-7345

VL - 61

SP - 6791

EP - 6794

JO - Chemical Communications

JF - Chemical Communications

IS - 37

ER -

Photocatalytic reductive incorporation of carbon dioxide into double bonds

Abstract

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