Photobiocatalytic decarboxylation for olefin synthesis

Ioannis Zachos; Sarah Katharina Gaßmeyer; Daniel Bauer; Volker Sieber; Frank Hollmann; Robert Kourist

doi:10.1039/c4cc07276f

Photobiocatalytic decarboxylation for olefin synthesis

Ioannis Zachos, Sarah Katharina Gaßmeyer, Daniel Bauer, Volker Sieber, Frank Hollmann, Robert Kourist

Chair of Chemistry of Biogenic Resources

Research output: Contribution to journal › Article › peer-review

95 Scopus citations

Abstract

Here, we describe the combination of OleT_JE with a light-driven in situ H₂O₂-generation system for the selective and quantitative conversion of fatty acids into terminal alkenes. The photobiocatalytic system shows clear advantages regarding enzyme activity and yield, resulting in a simple and efficient system for fatty acid decarboxylation.

Original language	English
Pages (from-to)	1918-1921
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	10
DOIs	https://doi.org/10.1039/c4cc07276f
State	Published - 4 Feb 2015

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title = "Photobiocatalytic decarboxylation for olefin synthesis",

abstract = "Here, we describe the combination of OleTJE with a light-driven in situ H2O2-generation system for the selective and quantitative conversion of fatty acids into terminal alkenes. The photobiocatalytic system shows clear advantages regarding enzyme activity and yield, resulting in a simple and efficient system for fatty acid decarboxylation.",

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AU - Zachos, Ioannis

AU - Gaßmeyer, Sarah Katharina

AU - Bauer, Daniel

AU - Sieber, Volker

AU - Hollmann, Frank

AU - Kourist, Robert

N1 - Publisher Copyright: © The Royal Society of Chemistry 2015.

PY - 2015/2/4

Y1 - 2015/2/4

N2 - Here, we describe the combination of OleTJE with a light-driven in situ H2O2-generation system for the selective and quantitative conversion of fatty acids into terminal alkenes. The photobiocatalytic system shows clear advantages regarding enzyme activity and yield, resulting in a simple and efficient system for fatty acid decarboxylation.

AB - Here, we describe the combination of OleTJE with a light-driven in situ H2O2-generation system for the selective and quantitative conversion of fatty acids into terminal alkenes. The photobiocatalytic system shows clear advantages regarding enzyme activity and yield, resulting in a simple and efficient system for fatty acid decarboxylation.

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U2 - 10.1039/c4cc07276f

DO - 10.1039/c4cc07276f

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AN - SCOPUS:84921685440

SN - 1359-7345

VL - 51

SP - 1918

EP - 1921

JO - Chemical Communications

JF - Chemical Communications

IS - 10

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Photobiocatalytic decarboxylation for olefin synthesis

Abstract

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