Photo-induced tautomerisation of methyltrioxorhenium(VII): The intermediate in olefin metathesis?

Leigh J. Morris; Anthony J. Downs; Tim M. Greene; G. Sean McGrady; Wolfgang A. Herrmann; Peter Sirsch; Odd Gropen; Wolfgang Scherer

doi:10.1039/a907908d

Photo-induced tautomerisation of methyltrioxorhenium(VII): The intermediate in olefin metathesis?

Leigh J. Morris
, Anthony J. Downs
, Tim M. Greene
, G. Sean McGrady
, Wolfgang A. Herrmann
, Peter Sirsch
, Odd Gropen
, Wolfgang Scherer

Technical University of Munich

University of Oxford
King's College London
Technical University of Munich
UIT The Arctic University of Norway

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

Matrix-isolated [CH₃ReO₃] tautomerises to [H₂C=Re(O)₂OH] under the influence of UV light; the carbene has been characterised in its normal and ²H- and ¹³C-enriched isotopic forms by its IR spectrum with results well replicated by quantum chemical calculations.

Original language	English
Pages (from-to)	67-68
Number of pages	2
Journal	Chemical Communications
Issue number	1
DOIs	https://doi.org/10.1039/a907908d
State	Published - 7 Jan 2000

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title = "Photo-induced tautomerisation of methyltrioxorhenium(VII): The intermediate in olefin metathesis?",

abstract = "Matrix-isolated [CH3ReO3] tautomerises to [H2C=Re(O)2OH] under the influence of UV light; the carbene has been characterised in its normal and 2H- and 13C-enriched isotopic forms by its IR spectrum with results well replicated by quantum chemical calculations.",

author = "Morris, \{Leigh J.\} and Downs, \{Anthony J.\} and Greene, \{Tim M.\} and McGrady, \{G. Sean\} and Herrmann, \{Wolfgang A.\} and Peter Sirsch and Odd Gropen and Wolfgang Scherer",

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doi = "10.1039/a907908d",

language = "English",

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journal = "Chemical Communications",

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T1 - Photo-induced tautomerisation of methyltrioxorhenium(VII)

T2 - The intermediate in olefin metathesis?

AU - Morris, Leigh J.

AU - Downs, Anthony J.

AU - Greene, Tim M.

AU - McGrady, G. Sean

AU - Herrmann, Wolfgang A.

AU - Sirsch, Peter

AU - Gropen, Odd

AU - Scherer, Wolfgang

PY - 2000/1/7

Y1 - 2000/1/7

N2 - Matrix-isolated [CH3ReO3] tautomerises to [H2C=Re(O)2OH] under the influence of UV light; the carbene has been characterised in its normal and 2H- and 13C-enriched isotopic forms by its IR spectrum with results well replicated by quantum chemical calculations.

AB - Matrix-isolated [CH3ReO3] tautomerises to [H2C=Re(O)2OH] under the influence of UV light; the carbene has been characterised in its normal and 2H- and 13C-enriched isotopic forms by its IR spectrum with results well replicated by quantum chemical calculations.

UR - https://www.scopus.com/pages/publications/0034614428

U2 - 10.1039/a907908d

DO - 10.1039/a907908d

M3 - Article

AN - SCOPUS:0034614428

SN - 1359-7345

SP - 67

EP - 68

JO - Chemical Communications

JF - Chemical Communications

IS - 1

ER -

Photo-induced tautomerisation of methyltrioxorhenium(VII): The intermediate in olefin metathesis?

Abstract

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