Photo-induced tautomerisation of methyltrioxorhenium(VII): The intermediate in olefin metathesis?

Leigh J. Morris; Anthony J. Downs; Tim M. Greene; G. Sean McGrady; Wolfgang A. Herrmann; Peter Sirsch; Odd Gropen; Wolfgang Scherer

doi:10.1039/a907908d

Photo-induced tautomerisation of methyltrioxorhenium(VII): The intermediate in olefin metathesis?

Leigh J. Morris, Anthony J. Downs, Tim M. Greene, G. Sean McGrady, Wolfgang A. Herrmann, Peter Sirsch, Odd Gropen, Wolfgang Scherer

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

Matrix-isolated [CH₃ReO₃] tautomerises to [H₂C=Re(O)₂OH] under the influence of UV light; the carbene has been characterised in its normal and ²H- and ¹³C-enriched isotopic forms by its IR spectrum with results well replicated by quantum chemical calculations.

Original language	English
Pages (from-to)	67-68
Number of pages	2
Journal	Chemical Communications
Issue number	1
DOIs	https://doi.org/10.1039/a907908d
State	Published - 7 Jan 2000

Access to Document

10.1039/a907908d

Cite this

@article{2e30abe43fab44cbac35ada5e2200a34,

title = "Photo-induced tautomerisation of methyltrioxorhenium(VII): The intermediate in olefin metathesis?",

abstract = "Matrix-isolated [CH3ReO3] tautomerises to [H2C=Re(O)2OH] under the influence of UV light; the carbene has been characterised in its normal and 2H- and 13C-enriched isotopic forms by its IR spectrum with results well replicated by quantum chemical calculations.",

author = "Morris, {Leigh J.} and Downs, {Anthony J.} and Greene, {Tim M.} and McGrady, {G. Sean} and Herrmann, {Wolfgang A.} and Peter Sirsch and Odd Gropen and Wolfgang Scherer",

year = "2000",

month = jan,

day = "7",

doi = "10.1039/a907908d",

language = "English",

pages = "67--68",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "1",

}

TY - JOUR

T1 - Photo-induced tautomerisation of methyltrioxorhenium(VII)

T2 - The intermediate in olefin metathesis?

AU - Morris, Leigh J.

AU - Downs, Anthony J.

AU - Greene, Tim M.

AU - McGrady, G. Sean

AU - Herrmann, Wolfgang A.

AU - Sirsch, Peter

AU - Gropen, Odd

AU - Scherer, Wolfgang

PY - 2000/1/7

Y1 - 2000/1/7

N2 - Matrix-isolated [CH3ReO3] tautomerises to [H2C=Re(O)2OH] under the influence of UV light; the carbene has been characterised in its normal and 2H- and 13C-enriched isotopic forms by its IR spectrum with results well replicated by quantum chemical calculations.

AB - Matrix-isolated [CH3ReO3] tautomerises to [H2C=Re(O)2OH] under the influence of UV light; the carbene has been characterised in its normal and 2H- and 13C-enriched isotopic forms by its IR spectrum with results well replicated by quantum chemical calculations.

UR - http://www.scopus.com/inward/record.url?scp=0034614428&partnerID=8YFLogxK

U2 - 10.1039/a907908d

DO - 10.1039/a907908d

M3 - Article

AN - SCOPUS:0034614428

SN - 1359-7345

SP - 67

EP - 68

JO - Chemical Communications

JF - Chemical Communications

IS - 1

ER -

Photo-induced tautomerisation of methyltrioxorhenium(VII): The intermediate in olefin metathesis?

Abstract

Access to Document

Other files and links

Fingerprint

Cite this