Photo- and γ-radiation-induced cycloaddition in the system cyclohexene-n-ethylmaleimide

E. Wipfelder; H. Heusinger

doi:10.1016/0146-5724(78)90031-6

Photo- and γ-radiation-induced cycloaddition in the system cyclohexene-n-ethylmaleimide

E. Wipfelder
, H. Heusinger

Radiochemistry Munich

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

In the photolysis as well as in the radiolysis of the system cyclohexene N-ethylmaleimide three isomeric bicyclo(4,2,0)ctane-7,8-dicarboxylic acid-N-ethylimides were found. The conformations {A figure is presented} were determined by mass spectrometry and NMR spectroscopy. The ratio of the isomers is almost equal in photolysis and radiolysis. Based on the experimental results a recombination of radical ions is proposed for 1:1-adduct formation in photolysis as well as in radiolysis.

Original language	English
Pages (from-to)	165-173
Number of pages	9
Journal	Radiation Physics and Chemistry
Volume	12
Issue number	5-6
DOIs	https://doi.org/10.1016/0146-5724(78)90031-6
State	Published - 1978

Access to Document

10.1016/0146-5724(78)90031-6

Cite this

@article{27ac84f0096e4464b664af50ae75fbba,

title = "Photo- and γ-radiation-induced cycloaddition in the system cyclohexene-n-ethylmaleimide",

abstract = "In the photolysis as well as in the radiolysis of the system cyclohexene N-ethylmaleimide three isomeric bicyclo(4,2,0)ctane-7,8-dicarboxylic acid-N-ethylimides were found. The conformations \{A figure is presented\} were determined by mass spectrometry and NMR spectroscopy. The ratio of the isomers is almost equal in photolysis and radiolysis. Based on the experimental results a recombination of radical ions is proposed for 1:1-adduct formation in photolysis as well as in radiolysis.",

author = "E. Wipfelder and H. Heusinger",

year = "1978",

doi = "10.1016/0146-5724(78)90031-6",

language = "English",

volume = "12",

pages = "165--173",

journal = "Radiation Physics and Chemistry",

issn = "0146-5724",

publisher = "Elsevier B.V.",

number = "5-6",

}

TY - JOUR

T1 - Photo- and γ-radiation-induced cycloaddition in the system cyclohexene-n-ethylmaleimide

AU - Wipfelder, E.

AU - Heusinger, H.

PY - 1978

Y1 - 1978

N2 - In the photolysis as well as in the radiolysis of the system cyclohexene N-ethylmaleimide three isomeric bicyclo(4,2,0)ctane-7,8-dicarboxylic acid-N-ethylimides were found. The conformations {A figure is presented} were determined by mass spectrometry and NMR spectroscopy. The ratio of the isomers is almost equal in photolysis and radiolysis. Based on the experimental results a recombination of radical ions is proposed for 1:1-adduct formation in photolysis as well as in radiolysis.

AB - In the photolysis as well as in the radiolysis of the system cyclohexene N-ethylmaleimide three isomeric bicyclo(4,2,0)ctane-7,8-dicarboxylic acid-N-ethylimides were found. The conformations {A figure is presented} were determined by mass spectrometry and NMR spectroscopy. The ratio of the isomers is almost equal in photolysis and radiolysis. Based on the experimental results a recombination of radical ions is proposed for 1:1-adduct formation in photolysis as well as in radiolysis.

UR - https://www.scopus.com/pages/publications/49349138963

U2 - 10.1016/0146-5724(78)90031-6

DO - 10.1016/0146-5724(78)90031-6

M3 - Article

AN - SCOPUS:49349138963

SN - 0146-5724

VL - 12

SP - 165

EP - 173

JO - Radiation Physics and Chemistry

JF - Radiation Physics and Chemistry

IS - 5-6

ER -

Photo- and γ-radiation-induced cycloaddition in the system cyclohexene-n-ethylmaleimide

Abstract

Access to Document

Other files and links

Fingerprint

Cite this