TY - JOUR
T1 - Phosphorus Analogues of Unsaturated Carbon Compounds
T2 - an (s‐trans)‐1,3‐Diphospha‐4‐metallabutadiene and Its (s‐cis)‐Fe(CO)3 Complex
AU - Karsch, Hans H.
AU - Reisacher, Hans‐Ulrich ‐U
AU - Huber, Brigitte
AU - Müller, Gerhard
AU - Malisch, Wolfgang
AU - Jörg, Klaus
PY - 1986/5
Y1 - 1986/5
N2 - s‐trans Configurated 1,3,‐diphospha‐4‐metallabutadienes 1 form green, air‐stable crystals (M = Mo, W; R = 2,4,6‐tBu3C6H2). When M = W, 1 reacts like butadiene itself with Fe(CO)3 to give the stable complex 2, in which the WPCP moiety is almost planar. (Figure Presented.)
AB - s‐trans Configurated 1,3,‐diphospha‐4‐metallabutadienes 1 form green, air‐stable crystals (M = Mo, W; R = 2,4,6‐tBu3C6H2). When M = W, 1 reacts like butadiene itself with Fe(CO)3 to give the stable complex 2, in which the WPCP moiety is almost planar. (Figure Presented.)
UR - http://www.scopus.com/inward/record.url?scp=84985614993&partnerID=8YFLogxK
U2 - 10.1002/anie.198604551
DO - 10.1002/anie.198604551
M3 - Article
AN - SCOPUS:84985614993
SN - 0570-0833
VL - 25
SP - 455
EP - 456
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 5
ER -