Phosphinosilylenes as a novel ligand system for heterobimetallic complexes

Nora C. Breit; Carsten Eisenhut; Shigeyoshi Inoue

doi:10.1039/c6cc00601a

Phosphinosilylenes as a novel ligand system for heterobimetallic complexes

Nora C. Breit
, Carsten Eisenhut
, Shigeyoshi Inoue

Chair of Silicon Chemistry

Technische Universität Berlin

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

A dihydrophosphinosilylene iron complex [LSi{Fe(CO)₄}PH₂] has been prepared and utilized in the synthesis of novel heterobimetallic complexes. The phosphine moiety in this phosphinosilylene complex allows coordination towards tungsten leading to the iron-tungsten heterobimetallic complex [LSi{Fe(CO)₄}PH₂{W(CO)₅}]. In contrast, the reaction of [LSi{Fe(CO)₄}PH₂] with ethylenebis(triphenylphosphine)platinum(0) results in the formation of the iron-platinum heterobimetallic complex [LSi{Fe(CO)₄}PH{PtH(PPh₃)₂}] via oxidative addition.

Original language	English
Pages (from-to)	5523-5526
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	32
DOIs	https://doi.org/10.1039/c6cc00601a
State	Published - 25 Apr 2016

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title = "Phosphinosilylenes as a novel ligand system for heterobimetallic complexes",

abstract = "A dihydrophosphinosilylene iron complex [LSi\{Fe(CO)4\}PH2] has been prepared and utilized in the synthesis of novel heterobimetallic complexes. The phosphine moiety in this phosphinosilylene complex allows coordination towards tungsten leading to the iron-tungsten heterobimetallic complex [LSi\{Fe(CO)4\}PH2\{W(CO)5\}]. In contrast, the reaction of [LSi\{Fe(CO)4\}PH2] with ethylenebis(triphenylphosphine)platinum(0) results in the formation of the iron-platinum heterobimetallic complex [LSi\{Fe(CO)4\}PH\{PtH(PPh3)2\}] via oxidative addition.",

author = "Breit, \{Nora C.\} and Carsten Eisenhut and Shigeyoshi Inoue",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2016.",

year = "2016",

month = apr,

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doi = "10.1039/c6cc00601a",

language = "English",

volume = "52",

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journal = "Chemical Communications",

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T1 - Phosphinosilylenes as a novel ligand system for heterobimetallic complexes

AU - Breit, Nora C.

AU - Eisenhut, Carsten

AU - Inoue, Shigeyoshi

PY - 2016/4/25

Y1 - 2016/4/25

N2 - A dihydrophosphinosilylene iron complex [LSi{Fe(CO)4}PH2] has been prepared and utilized in the synthesis of novel heterobimetallic complexes. The phosphine moiety in this phosphinosilylene complex allows coordination towards tungsten leading to the iron-tungsten heterobimetallic complex [LSi{Fe(CO)4}PH2{W(CO)5}]. In contrast, the reaction of [LSi{Fe(CO)4}PH2] with ethylenebis(triphenylphosphine)platinum(0) results in the formation of the iron-platinum heterobimetallic complex [LSi{Fe(CO)4}PH{PtH(PPh3)2}] via oxidative addition.

AB - A dihydrophosphinosilylene iron complex [LSi{Fe(CO)4}PH2] has been prepared and utilized in the synthesis of novel heterobimetallic complexes. The phosphine moiety in this phosphinosilylene complex allows coordination towards tungsten leading to the iron-tungsten heterobimetallic complex [LSi{Fe(CO)4}PH2{W(CO)5}]. In contrast, the reaction of [LSi{Fe(CO)4}PH2] with ethylenebis(triphenylphosphine)platinum(0) results in the formation of the iron-platinum heterobimetallic complex [LSi{Fe(CO)4}PH{PtH(PPh3)2}] via oxidative addition.

UR - https://www.scopus.com/pages/publications/84964584496

U2 - 10.1039/c6cc00601a

DO - 10.1039/c6cc00601a

M3 - Article

AN - SCOPUS:84964584496

SN - 1359-7345

VL - 52

SP - 5523

EP - 5526

JO - Chemical Communications

JF - Chemical Communications

IS - 32

ER -

Phosphinosilylenes as a novel ligand system for heterobimetallic complexes

Abstract

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