Phosphine complexes of main group elements. [(Me3Si)C(PMe 2)2]2Ge2I2, an intramolecular germylene (germanediyl) donor-germylene acceptor complex with a germylene-phosphane chelating ligand

Hans H. Karsch; Josef Hofmann; Gerhard Müller

doi:10.1039/C39880000516

Phosphine complexes of main group elements. [(Me₃Si)C(PMe ₂)₂]₂Ge₂I₂, an intramolecular germylene (germanediyl) donor-germylene acceptor complex with a germylene-phosphane chelating ligand

Hans H. Karsch
, Josef Hofmann
, Gerhard Müller

Natural Sciences

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

The addition of I₂ to the bis-germylene complex [(Me ₃Si)C(PMe₂)₂]₂Ge₂ (Ge^I-Ge^I) (1) surprisingly results in the oxidation of only one Ge atom and rearrangement of one of the phosphinomethanide ligands; the Gel₂ formed is complexed by a chelating germylene-phosphine ligand in the form of a homonuclear donor-acceptor complex.

Original language	English
Pages (from-to)	516-517
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	8
DOIs	https://doi.org/10.1039/C39880000516
State	Published - 1988

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title = "Phosphine complexes of main group elements. [(Me3Si)C(PMe 2)2]2Ge2I2, an intramolecular germylene (germanediyl) donor-germylene acceptor complex with a germylene-phosphane chelating ligand",

abstract = "The addition of I2 to the bis-germylene complex [(Me 3Si)C(PMe2)2]2Ge2 (GeI-GeI) (1) surprisingly results in the oxidation of only one Ge atom and rearrangement of one of the phosphinomethanide ligands; the Gel2 formed is complexed by a chelating germylene-phosphine ligand in the form of a homonuclear donor-acceptor complex.",

author = "Karsch, \{Hans H.\} and Josef Hofmann and Gerhard M{\"u}ller",

year = "1988",

doi = "10.1039/C39880000516",

language = "English",

pages = "516--517",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

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Phosphine complexes of main group elements. [(Me₃Si)C(PMe ₂)₂]₂Ge₂I₂, an intramolecular germylene (germanediyl) donor-germylene acceptor complex with a germylene-phosphane chelating ligand. / Karsch, Hans H.; Hofmann, Josef; Müller, Gerhard.
In: Journal of the Chemical Society, Chemical Communications, No. 8, 1988, p. 516-517.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Phosphine complexes of main group elements. [(Me3Si)C(PMe 2)2]2Ge2I2, an intramolecular germylene (germanediyl) donor-germylene acceptor complex with a germylene-phosphane chelating ligand

AU - Karsch, Hans H.

AU - Hofmann, Josef

AU - Müller, Gerhard

PY - 1988

Y1 - 1988

N2 - The addition of I2 to the bis-germylene complex [(Me 3Si)C(PMe2)2]2Ge2 (GeI-GeI) (1) surprisingly results in the oxidation of only one Ge atom and rearrangement of one of the phosphinomethanide ligands; the Gel2 formed is complexed by a chelating germylene-phosphine ligand in the form of a homonuclear donor-acceptor complex.

AB - The addition of I2 to the bis-germylene complex [(Me 3Si)C(PMe2)2]2Ge2 (GeI-GeI) (1) surprisingly results in the oxidation of only one Ge atom and rearrangement of one of the phosphinomethanide ligands; the Gel2 formed is complexed by a chelating germylene-phosphine ligand in the form of a homonuclear donor-acceptor complex.

UR - https://www.scopus.com/pages/publications/37049067316

U2 - 10.1039/C39880000516

DO - 10.1039/C39880000516

M3 - Article

AN - SCOPUS:37049067316

SN - 0022-4936

SP - 516

EP - 517

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 8

ER -

Phosphine complexes of main group elements. [(Me₃Si)C(PMe ₂)₂]₂Ge₂I₂, an intramolecular germylene (germanediyl) donor-germylene acceptor complex with a germylene-phosphane chelating ligand

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