Phosphine complexes of main group elements: Crystal structure of {Li[C(PMe2)3]-(tetrahydrofuran)}2

Hans H. Karsch; Gerhard Müller

doi:10.1039/C39840000569

Phosphine complexes of main group elements: Crystal structure of {Li[C(PMe₂)₃]-(tetrahydrofuran)}₂

Hans H. Karsch
, Gerhard Müller

Natural Sciences

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

32 Scopus citations

Abstract

The X-ray structure determination of the title compound, obtained by recrystallisation of LiC(PMe₂)₃ from pentane- tetrahydrofuran (thf) as colourless crystals, reveals it to be dimeric with two nearly planar (Me₂P)₃C-moieties linked by (thf)Li fragments via chelating and additional π-type interactions.

Original language	English
Pages (from-to)	569-570
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	9
DOIs	https://doi.org/10.1039/C39840000569
State	Published - 1984

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title = "Phosphine complexes of main group elements: Crystal structure of \{Li[C(PMe2)3]-(tetrahydrofuran)\}2",

abstract = "The X-ray structure determination of the title compound, obtained by recrystallisation of LiC(PMe2)3 from pentane- tetrahydrofuran (thf) as colourless crystals, reveals it to be dimeric with two nearly planar (Me2P)3C-moieties linked by (thf)Li fragments via chelating and additional π-type interactions.",

author = "Karsch, \{Hans H.\} and Gerhard M{\"u}ller",

year = "1984",

doi = "10.1039/C39840000569",

language = "English",

pages = "569--570",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "9",

}

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T1 - Phosphine complexes of main group elements

T2 - Crystal structure of {Li[C(PMe2)3]-(tetrahydrofuran)}2

AU - Karsch, Hans H.

AU - Müller, Gerhard

PY - 1984

Y1 - 1984

N2 - The X-ray structure determination of the title compound, obtained by recrystallisation of LiC(PMe2)3 from pentane- tetrahydrofuran (thf) as colourless crystals, reveals it to be dimeric with two nearly planar (Me2P)3C-moieties linked by (thf)Li fragments via chelating and additional π-type interactions.

AB - The X-ray structure determination of the title compound, obtained by recrystallisation of LiC(PMe2)3 from pentane- tetrahydrofuran (thf) as colourless crystals, reveals it to be dimeric with two nearly planar (Me2P)3C-moieties linked by (thf)Li fragments via chelating and additional π-type interactions.

UR - https://www.scopus.com/pages/publications/37049109270

U2 - 10.1039/C39840000569

DO - 10.1039/C39840000569

M3 - Article

AN - SCOPUS:37049109270

SN - 0022-4936

SP - 569

EP - 570

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 9

ER -

Phosphine complexes of main group elements: Crystal structure of {Li[C(PMe₂)₃]-(tetrahydrofuran)}₂

Abstract

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