Phosphine complexes of main group elements: Crystal structure of {Li[C(PMe2)3]-(tetrahydrofuran)}2

Hans H. Karsch, Gerhard Müller

Research output: Contribution to journalArticlepeer-review

32 Scopus citations

Abstract

The X-ray structure determination of the title compound, obtained by recrystallisation of LiC(PMe2)3 from pentane- tetrahydrofuran (thf) as colourless crystals, reveals it to be dimeric with two nearly planar (Me2P)3C-moieties linked by (thf)Li fragments via chelating and additional π-type interactions.

Original languageEnglish
Pages (from-to)569-570
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number9
DOIs
StatePublished - 1984

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