Petrographic and trace-element distribution studies on the dolomite-calcite in the regional metamorphic marble of the Griesscharte, Tyrol, Austria/Italy

Petrographic investigations on the light yellow marble outcrops in the Griesscharte, Tyrol, Austria/Italy revealed them to be dolomite. The white to blue-grey veins in these marbles were those of calcite. Inside these calcites and along the calcite-dolomite phase boundaries minute and microscopically unidentifiable crystallites (≤ 10 μ) were observed. These crystallites were recognised by X-ray diffractometry as dolomite and their form and distribution were established by scanning electron microscopy. Trace-element distributions on the calcite-dolomite neighbours were studied by neutron-activation method to elucidate the formation mechanism of these calcites in the marble. Genetic relationships of the dolomite crystallites, the calcite host and the surrounding dolomite marble have been discussed in the light of the petrographic and chemical studies. These findings substantiate a deposition of a new formed vein of calcite from the solution circulating in the fissures of the dolomite marble during prograde metamorphism rather than a simple deposition of mobilized sedimentary calcite. The dolomite crystallites in the calcite seem to have been formed post-tectonically, partly by the nucleation in the calcite cleavage planes during Mg-metasomatism and partly from the exsolutions during retrograde metamorphism.