[Pd3(InCp*)4 (μ2-InCp*)4]: Three linearly arranged palladium atoms wrapped into a fluxional shell of eight InCp* Ligands

Tobias Steinke; Christian Gemel; Manuela Winter; Roland A. Fischer

doi:10.1002/anie.200290041

[Pd₃(InCp)₄ (μ₂-InCp)₄]: Three linearly arranged palladium atoms wrapped into a fluxional shell of eight InCp* Ligands

Tobias Steinke
, Christian Gemel
, Manuela Winter
, Roland A. Fischer

Max-Planck-lnstitut für Kohlenforschung

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

There is still much to discover: The assumption that monovalent Group 13 organometallic compounds exhibit a high potential as ligands in organometallic chemistry beyond their analogy to CO is confirmed by the synthesis of the title compound 1. Complex 1, the structure of which is unique and has no analogue in carbonyl cluster chemistry, is prepared by reaction of [(tmeda)Pd(CH₃)₂] with [InCp*]. tmeda = N,N,N′,N′-tetramethylethylenediamine, Cp* = pentamethyl-cyclopentadienide.

Original language	English
Pages (from-to)	4761-4763
Number of pages	3
Journal	Angewandte Chemie International Edition in English
Volume	41
Issue number	24
DOIs	https://doi.org/10.1002/anie.200290041
State	Published - 16 Dec 2002
Externally published	Yes

Keywords

Cluster compounds
Cyclopentadienyl ligands
Group 13 elements
Indium
Palladium

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10.1002/anie.200290041

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title = "[Pd3(InCp*)4 (μ2-InCp*)4]: Three linearly arranged palladium atoms wrapped into a fluxional shell of eight InCp* Ligands",

abstract = "There is still much to discover: The assumption that monovalent Group 13 organometallic compounds exhibit a high potential as ligands in organometallic chemistry beyond their analogy to CO is confirmed by the synthesis of the title compound 1. Complex 1, the structure of which is unique and has no analogue in carbonyl cluster chemistry, is prepared by reaction of [(tmeda)Pd(CH3)2] with [InCp*]. tmeda = N,N,N′,N′-tetramethylethylenediamine, Cp* = pentamethyl-cyclopentadienide.",

keywords = "Cluster compounds, Cyclopentadienyl ligands, Group 13 elements, Indium, Palladium",

author = "Tobias Steinke and Christian Gemel and Manuela Winter and Fischer, \{Roland A.\}",

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language = "English",

volume = "41",

pages = "4761--4763",

journal = "Angewandte Chemie International Edition in English",

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T1 - [Pd3(InCp*)4 (μ2-InCp*)4]

T2 - Three linearly arranged palladium atoms wrapped into a fluxional shell of eight InCp* Ligands

AU - Steinke, Tobias

AU - Gemel, Christian

AU - Winter, Manuela

AU - Fischer, Roland A.

PY - 2002/12/16

Y1 - 2002/12/16

N2 - There is still much to discover: The assumption that monovalent Group 13 organometallic compounds exhibit a high potential as ligands in organometallic chemistry beyond their analogy to CO is confirmed by the synthesis of the title compound 1. Complex 1, the structure of which is unique and has no analogue in carbonyl cluster chemistry, is prepared by reaction of [(tmeda)Pd(CH3)2] with [InCp*]. tmeda = N,N,N′,N′-tetramethylethylenediamine, Cp* = pentamethyl-cyclopentadienide.

AB - There is still much to discover: The assumption that monovalent Group 13 organometallic compounds exhibit a high potential as ligands in organometallic chemistry beyond their analogy to CO is confirmed by the synthesis of the title compound 1. Complex 1, the structure of which is unique and has no analogue in carbonyl cluster chemistry, is prepared by reaction of [(tmeda)Pd(CH3)2] with [InCp*]. tmeda = N,N,N′,N′-tetramethylethylenediamine, Cp* = pentamethyl-cyclopentadienide.

KW - Cluster compounds

KW - Cyclopentadienyl ligands

KW - Group 13 elements

KW - Indium

KW - Palladium

UR - https://www.scopus.com/pages/publications/0037122050

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DO - 10.1002/anie.200290041

M3 - Article

AN - SCOPUS:0037122050

SN - 1433-7851

VL - 41

SP - 4761

EP - 4763

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 24

ER -

[Pd₃(InCp)₄ (μ₂-InCp)₄]: Three linearly arranged palladium atoms wrapped into a fluxional shell of eight InCp* Ligands

Abstract

Keywords

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