Pd/C as a highly active catalyst for Heck, Suzuki and Sonogashira reactions

Roland G. Heidenreich; Klaus Köhler; Jürgen G.E. Krauter; Jörg Pietsch

doi:10.1055/s-2002-32589

Pd/C as a highly active catalyst for Heck, Suzuki and Sonogashira reactions

Roland G. Heidenreich, Klaus Köhler, Jürgen G.E. Krauter, Jörg Pietsch

Associate Professorship of Inorganic Chemistry

Research output: Contribution to journal › Article › peer-review

229 Scopus citations

Abstract

A specially optimized air-stable Pd on activated carbon catalyst is demonstrated to be a highly active (TON up to 36,000), selective and convenient heterogeneous catalyst for CC couplings of aryl halides in Heck, Suzuki, and Sonogashira reactions. The Pd/C catalyst developed allows extremely low Pd concentrations (down to 0.0025 mol% for Heck coupling, 0.005 mol% for Suzuki coupling) and high conversions of aryl bromides within a few hours. Easy and complete Pd separation and recovery is possible.

Original language	English
Pages (from-to)	1118-1122
Number of pages	5
Journal	Synlett
Issue number	7
DOIs	https://doi.org/10.1055/s-2002-32589
State	Published - 2002

Keywords

Aryl halides
Catalysis
Coupling
Heterogeneous
Palladium

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title = "Pd/C as a highly active catalyst for Heck, Suzuki and Sonogashira reactions",

abstract = "A specially optimized air-stable Pd on activated carbon catalyst is demonstrated to be a highly active (TON up to 36,000), selective and convenient heterogeneous catalyst for CC couplings of aryl halides in Heck, Suzuki, and Sonogashira reactions. The Pd/C catalyst developed allows extremely low Pd concentrations (down to 0.0025 mol% for Heck coupling, 0.005 mol% for Suzuki coupling) and high conversions of aryl bromides within a few hours. Easy and complete Pd separation and recovery is possible.",

keywords = "Aryl halides, Catalysis, Coupling, Heterogeneous, Palladium",

author = "Heidenreich, {Roland G.} and Klaus K{\"o}hler and Krauter, {J{\"u}rgen G.E.} and J{\"o}rg Pietsch",

year = "2002",

doi = "10.1055/s-2002-32589",

language = "English",

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AU - Heidenreich, Roland G.

AU - Köhler, Klaus

AU - Krauter, Jürgen G.E.

AU - Pietsch, Jörg

PY - 2002

Y1 - 2002

N2 - A specially optimized air-stable Pd on activated carbon catalyst is demonstrated to be a highly active (TON up to 36,000), selective and convenient heterogeneous catalyst for CC couplings of aryl halides in Heck, Suzuki, and Sonogashira reactions. The Pd/C catalyst developed allows extremely low Pd concentrations (down to 0.0025 mol% for Heck coupling, 0.005 mol% for Suzuki coupling) and high conversions of aryl bromides within a few hours. Easy and complete Pd separation and recovery is possible.

AB - A specially optimized air-stable Pd on activated carbon catalyst is demonstrated to be a highly active (TON up to 36,000), selective and convenient heterogeneous catalyst for CC couplings of aryl halides in Heck, Suzuki, and Sonogashira reactions. The Pd/C catalyst developed allows extremely low Pd concentrations (down to 0.0025 mol% for Heck coupling, 0.005 mol% for Suzuki coupling) and high conversions of aryl bromides within a few hours. Easy and complete Pd separation and recovery is possible.

KW - Aryl halides

KW - Catalysis

KW - Coupling

KW - Heterogeneous

KW - Palladium

UR - http://www.scopus.com/inward/record.url?scp=0036062734&partnerID=8YFLogxK

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DO - 10.1055/s-2002-32589

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JO - Synlett

JF - Synlett

IS - 7

ER -

Pd/C as a highly active catalyst for Heck, Suzuki and Sonogashira reactions

Abstract

Keywords

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