Partial double bond character in chalcogen compounds of stanna-closo-dodecaborate

Marius Kirchmann; Torben Gädt; Falko M. Schappacher; Rainer Pöttgen; Florian Weigend; Lars Wesemann

doi:10.1039/b814936d

Partial double bond character in chalcogen compounds of stanna-closo-dodecaborate

Marius Kirchmann, Torben Gädt, Falko M. Schappacher, Rainer Pöttgen, Florian Weigend, Lars Wesemann

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

The following chalcogen compounds of stanna-closo-dodecaborate were synthesized and characterized: the tetrameric oxide [(O-SnB₁₁H ₁₁)₄]^8- from the reaction with hydrogen peroxide and the sulfide and selenide [S-SnB₁₁H₁₁] ^2-, [Se-SnB₁₁H₁₁]^2- from the reaction with elemental sulfur and selenium, respectively. The stannaborate derivatives were characterized by ¹¹⁹Sn Mössbauer spectroscopy and single crystal structural analysis. The character of the bond between the tin and group 16 elements was studied extensively by using quantum chemical methods.

Original language	English
Pages (from-to)	1055-1062
Number of pages	8
Journal	Dalton Transactions
Issue number	6
DOIs	https://doi.org/10.1039/b814936d
State	Published - 2009
Externally published	Yes

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title = "Partial double bond character in chalcogen compounds of stanna-closo-dodecaborate",

abstract = "The following chalcogen compounds of stanna-closo-dodecaborate were synthesized and characterized: the tetrameric oxide [(O-SnB11H 11)4]8- from the reaction with hydrogen peroxide and the sulfide and selenide [S-SnB11H11] 2-, [Se-SnB11H11]2- from the reaction with elemental sulfur and selenium, respectively. The stannaborate derivatives were characterized by 119Sn M{\"o}ssbauer spectroscopy and single crystal structural analysis. The character of the bond between the tin and group 16 elements was studied extensively by using quantum chemical methods.",

author = "Marius Kirchmann and Torben G{\"a}dt and Schappacher, {Falko M.} and Rainer P{\"o}ttgen and Florian Weigend and Lars Wesemann",

year = "2009",

doi = "10.1039/b814936d",

language = "English",

pages = "1055--1062",

journal = "Dalton Transactions",

issn = "1477-9226",

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T1 - Partial double bond character in chalcogen compounds of stanna-closo-dodecaborate

AU - Kirchmann, Marius

AU - Gädt, Torben

AU - Schappacher, Falko M.

AU - Pöttgen, Rainer

AU - Weigend, Florian

AU - Wesemann, Lars

PY - 2009

Y1 - 2009

N2 - The following chalcogen compounds of stanna-closo-dodecaborate were synthesized and characterized: the tetrameric oxide [(O-SnB11H 11)4]8- from the reaction with hydrogen peroxide and the sulfide and selenide [S-SnB11H11] 2-, [Se-SnB11H11]2- from the reaction with elemental sulfur and selenium, respectively. The stannaborate derivatives were characterized by 119Sn Mössbauer spectroscopy and single crystal structural analysis. The character of the bond between the tin and group 16 elements was studied extensively by using quantum chemical methods.

AB - The following chalcogen compounds of stanna-closo-dodecaborate were synthesized and characterized: the tetrameric oxide [(O-SnB11H 11)4]8- from the reaction with hydrogen peroxide and the sulfide and selenide [S-SnB11H11] 2-, [Se-SnB11H11]2- from the reaction with elemental sulfur and selenium, respectively. The stannaborate derivatives were characterized by 119Sn Mössbauer spectroscopy and single crystal structural analysis. The character of the bond between the tin and group 16 elements was studied extensively by using quantum chemical methods.

UR - http://www.scopus.com/inward/record.url?scp=62549146580&partnerID=8YFLogxK

U2 - 10.1039/b814936d

DO - 10.1039/b814936d

M3 - Article

AN - SCOPUS:62549146580

SN - 1477-9226

SP - 1055

EP - 1062

JO - Dalton Transactions

JF - Dalton Transactions

IS - 6

ER -

Partial double bond character in chalcogen compounds of stanna-closo-dodecaborate

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